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Electrostatic Control of Aromatic Stacking Interactions
Abstract
A supramolecular approach has been used to investigate the free energies of intermolecular aromatic stacking interactions. Chemical double mutant cycles have been used to measure the effect of a range of substituents on face-to-face stacking interactions with phenyl and pentafluorophenyl rings. Electrostatic effects dominate the trends in interaction energy.
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Cited by
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Salonen, L. M., Ellermann, M., & Diederich, F. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007560 · Cited by 1,539
Free-floating ultrathin two-dimensional crystals from sequence-specific peptoid polymers
Nam, K. T., Shelby, S. A., Choi, P. H., Marciel, A. B., Chen, R., Tan, L., Chu, T. K., Mesch, R. A., Lee, B.-C., Connolly, M. D., et al. (2010) · Nature Materials · doi:10.1038/nmat2742 · Cited by 417
Adsorption of Aromatic and Anti-Aromatic Systems on Graphene through π−π Stacking
Björk, J., Hanke, F., Palma, C.-A., Samori, P., Cecchini, M., & Persson, M. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz101360k · Cited by 409
Effects of Heteroatoms on Aromatic π−π Interactions: Benzene−Pyridine and Pyridine Dimer
Hohenstein, E. G., & Sherrill, C. D. (2009) · The Journal of Physical Chemistry A · doi:10.1021/jp809062x · Cited by 373
Chessari, G., Buck, I. M., Day, J. E. H., Day, P. J., Iqbal, A., Johnson, C. N., Lewis, E. J., Martins, V., Miller, D., Reader, M., et al. (2015) · Journal of Medicinal Chemistry · doi:10.1021/acs.jmedchem.5b00706 · Cited by 90
Metadata
- Authors
- Cockroft, S. L., Hunter, C. A., Lawson, K. R., Perkins, J., & Urch, C. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-05-28
- Volume
- 127
- Issue
- 24
- Pages
- 8594-8595
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1980097507
- Cited by
- 331
- References
- 0
- FWCI
- 9.47
- Type
- journal article
- Language
- en
- Open access
- closed
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- Cockroft, S. L., Hunter, C. A., Lawson, K. R., Perkins, J., & Urch, C. J. (2005). Electrostatic Control of Aromatic Stacking Interactions. Journal of the American Chemical Society. https://doi.org/10.1021/ja050880n
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
