The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Single-Component Catalyst/Initiators for the Organocatalytic Ring-Opening Polymerization of Lactide
Abstract
The synthesis and characterization of a series of primary and secondary alcohol adducts of 1,3-dimesitylimidazolin-2-ylidene is described. These adducts are stable as solids at room temperature, but readily release alcohol and the free carbene in solution. These alcohol adducts function as excellent single-component catalyst/initiators for the ring-opening polymerization of lactide under mild conditions, providing polymers with controlled molecular weights and narrow polydispersities. Multifunctional adducts were used to prepare poly(lactide)s of more complex architectures.
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Citations
Cites
Controlled Ring-Opening Polymerization of Lactide and Glycolide
Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257
Cited by
Organocatalysis by N-Heterocyclic Carbenes
Enders, D., Niemeier, O., & Henseler, A. (2007) · Chemical Reviews · doi:10.1021/cr068372z · Cited by 3,059
Organocatalytic Ring-Opening Polymerization
Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489
Self-citationOrganocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907
Self-citationFèvre, M., Pinaud, J., Gnanou, Y., Vignolle, J., & Taton, D. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35383k · Cited by 532
Complexes of Mg, Ca and Zn as homogeneous catalysts for lactide polymerization
Wheaton, C. A., Hayes, P. G., & Ireland, B. J. (2009) · Dalton Transactions · doi:10.1039/b819107g · Cited by 438
Metadata
- Authors
- Csihony, S., Culkin, D. A., Sentman, A. C., Dove, A. P., Waymouth, R. M., & Hedrick, J. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-06-01
- Volume
- 127
- Issue
- 25
- Pages
- 9079-9084
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1977421085
- Cited by
- 180
- References
- 1
- FWCI
- 7.99
- Type
- journal article
- Language
- en
- Open access
- closed
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