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γ-Fe2O3/II−VI Sulfide Nanocrystal Heterojunctions
Abstract
Heterostructure nanocrystals (NCs) of gamma-Fe(2)O(3) and MS (M = Zn, Cd, Hg) are synthesized. The large lattice mismatch between gamma-Fe(2)O(3) and MS NCs leads to noncentrosymmetric structures. Crystallographic planes at the heterojunctions are identified by high-resolution transmission electron microscopy. Preferential formation of trimers and higher oligomers for ZnS and dimers or isolated particles for CdS and HgS with gamma-Fe(2)O(3) NCs are observed and explained by changes in the effective mismatch between the coincidence lattices of the most commonly observed junction planes.
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Cites
Dabbousi, B. O., Rodriguez-Viejo, J., Mikulec, F. V., Heine, J. R., Mattoussi, H., Ober, R., Jensen, K. F., & Bawendi, M. G. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp971091y · Cited by 4,229
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Habas, S. E., Lee, H., Radmilovic, V., Somorjai, G. A., & Yang, P. (2007) · Nature Materials · doi:10.1038/nmat1957 · Cited by 1,205
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Zheng, Y., Zheng, L., Zhan, Y., Lin, X., Zheng, Q., & Wei, K. (2007) · Inorganic Chemistry · doi:10.1021/ic700688f · Cited by 913
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Cortie, M. B., & McDonagh, A. M. (2011) · Chemical Reviews · doi:10.1021/cr1002529 · Cited by 834
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Metadata
- Authors
- Kwon, K.-W., & Shim, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-07-01
- Volume
- 127
- Issue
- 29
- Pages
- 10269-10275
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2320831802
- Cited by
- 246
- References
- 1
- FWCI
- 10.48
- Type
- journal article
- Language
- en
- Open access
- closed
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