The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Small-Molecule Dynamics and Mechanisms Underlying the Macroscopic Mechanical Properties of Coordinatively Cross-Linked Polymer Networks
Abstract
Specific metal-ligand coordination between bis-Pd(II) and Pt(II) organometallic cross-linkers and poly(4-vinylpyridine) in DMSO defines a three-dimensional associative polymer network. Frequency-dependent dynamic mechanical moduli of a series of four different bulk materials, measured across several decades of oscillatory strain rates, are found to be quantitatively related through the pyridine exchange rates measured on model Pd(II) and Pt(II) complexes. Importantly, the mechanism of ligand exchange in the networks is found to be the same solvent-assisted pathway observed in the model complexes, and so the bulk mechanical properties are determined by relaxations that occur when the cross-links are dissociated from the polymer backbone. It is how often the cross-links dissociate, independently of how long they remain dissociated, that determines the bulk mechanical properties. The quantitative relationship between bulk materials properties and the kinetics and mechanisms observed in model compounds holds promise for the rational, molecular design of materials with tailored mechanical properties.
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Low Molecular Mass Gelators of Organic Liquids and the Properties of Their Gels
Terech, P., & Weiss, R. G. (1997) · Chemical Reviews · doi:10.1021/cr9700282 · Cited by 3,130
Brunsveld, L., Folmer, B. J. B., Meijer, E. W., & Sijbesma, R. P. (2001) · Chemical Reviews · doi:10.1021/cr990125q · Cited by 3,006
Reversible Polymers Formed from Self-Complementary Monomers Using Quadruple Hydrogen Bonding
Sijbesma, R. P., Beijer, F. H., Brunsveld, L., Folmer, B. J. B., Hirschberg, J. H. K. K., Lange, R. F. M., Lowe, J. K. L., & Meijer, E. W. (1997) · Science · doi:10.1126/science.278.5343.1601 · Cited by 2,393
Water Gelation by Small Organic Molecules
Estroff, L. A., & Hamilton, A. D. (2004) · Chemical Reviews · doi:10.1021/cr0302049 · Cited by 2,034
Robinson, B. H., & Kaler, E. W. (1999) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(00)00026-1 · Cited by 1,766
Statics and Dynamics of Wormlike Surfactant Micelles
Zhang, W. (1999) · China Surfactant Detergent & Cosmetics · Cited by 1,089
Statics and dynamics of worm-like surfactant micelles
Cates, M. E., & Candau, S. J. (1990) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/2/33/001 · Cited by 1,080
A New Approach to the Theory of Relaxing Polymeric Media
Green, M. S., & Tobolsky, A. V. (1946) · The Journal of Chemical Physics · doi:10.1063/1.1724109 · Cited by 889
Mechanisms of Inorganic Reactions
Edwards, J. O. (1966) · Inorganic Chemistry · doi:10.1021/ic50038a051 · Cited by 872
Annable, T., Buscall, R., Ettelaie, R., & Whittlestone, D. (1993) · Journal of Rheology · doi:10.1122/1.550391 · Cited by 784
Acceleration of a Diels–Alder reaction by a self-assembled molecular capsule
Kang, J., & Rebek, J. (1997) · Nature · doi:10.1038/385050a0 · Cited by 605
Thermoreversible Gelation in Solutions of Associating Polymers. 2. Linear Dynamics
Rubinstein, M., & Semenov, A. N. (1998) · Macromolecules · doi:10.1021/ma970617+ · Cited by 469
Yount, W. C., Loveless, D. M., & Craig, S. L. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500026 · Cited by 260
Self-citationInfrared remote sensing of breaking waves
Jessup, A. T., Zappa, C. J., Loewen, M. R., & Hesany, V. (1997) · Nature · doi:10.1038/385052a0 · Cited by 214
Yount, W. C., Juwarker, H., & Craig, S. L. (2003) · Journal of the American Chemical Society · doi:10.1021/ja036709y · Cited by 171
Self-citationTwo-Dimensional Melting of an Anisotropic Crystal Observed at the Molecular Level
Sikes, H. D., & Schwartz, D. K. (1997) · Science · doi:10.1126/science.278.5343.1604 · Cited by 148
Linear Rheology of Water-Soluble Reversible Neodymium(III) Coordination Polymers
Vermonden, T., van Steenbergen, M. J., Besseling, N. A. M., Marcelis, A. T. M., Hennink, W. E., Sudhölter, E. J. R., & Stuart, M. A. C. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0458928 · Cited by 139
Pollino, J. M., Nair, K. P., Stubbs, L. P., et al. (2004) · Tetrahedron · doi:10.1016/j.tet.2004.05.055 · Cited by 87
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Yan, X., Wang, F., Zheng, B., & Huang, F. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35091b · Cited by 1,631
Supramolecular polymeric hydrogels
Appel, E. A., del Barrio, J., Loh, X. J., & Scherman, O. A. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35264h · Cited by 1,159
Malleable and Self-Healing Covalent Polymer Networks through Tunable Dynamic Boronic Ester Bonds
Cromwell, O. R., Chung, J., & Guan, Z. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03551 · Cited by 1,048
Functional soft materials from metallopolymers and metallosupramolecular polymers
Whittell, G. R., Hager, M. D., Schubert, U. S., & Manners, I. (2011) · Nature Materials · doi:10.1038/nmat2966 · Cited by 1,013
Multifunctional Energy Storage and Conversion Devices
Huang, Y., Zhu, M., Huang, Y., Pei, Z., Li, H., Wang, Z., Xue, Q., & Zhi, C. (2016) · Advanced Materials · doi:10.1002/adma.201601928 · Cited by 544
Metadata
- Authors
- Yount, W. C., Loveless, D. M., & Craig, S. L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-09-22
- Volume
- 127
- Issue
- 41
- Pages
- 14488-14496
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2014313640
- Cited by
- 388
- References
- 18
- FWCI
- 6.95
- Type
- journal article
- Language
- en
- Open access
- closed
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