The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Functionalization of Single-Walled Carbon Nanotubes with Well-Defined Polystyrene by “Click” Coupling
Abstract
Covalent functionalization of alkyne-decorated SWNTs with well-defined, azide-terminated polystyrene polymers was accomplished by the Cu(I)-catalyzed [3 + 2] Huisgen cycloaddition. This reaction was found to be extremely efficient in producing organosoluble polymer-nanotube conjugates, even at relatively low reaction temperatures (60 degrees C) and short reaction times (24 h). The reaction was found to be most effective when a CuI catalyst was employed in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene as an additive. IR spectroscopy was utilized to follow the introduction and consumption of alkyne groups on the SWNTs, and Raman spectroscopy evidenced the conversion of a high proportion of sp(2) carbons to sp(3) hybridization during alkyne introduction. Thermogravimetric analysis indicated that the polymer-functionalized SWNTs consisted of 45% polymer, amounting to approximately one polymer chain for every 200-700 carbons of the nanotubes, depending on polymer molecular weight. Transmission electron microscopy and atomic force microscopy were utilized to image polymer-functionalized SWNTs, showing relatively uniform polymer coatings present on the surface of individual, debundled nanotubes.
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Citations
Cites
Spectrometric Identification of Organic Compounds
Silverstein, R. M., & Bassler, G. C. (1962) · Journal of Chemical Education · doi:10.1021/ed039p546 · Cited by 14,272
Tornøe, C. W., Christensen, C., & Meldal, M. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo011148j · Cited by 8,696
PEG- and Peptide-Grafted Aliphatic Polyesters by Click Chemistry
Parrish, B., Breitenkamp, R. B., & Emrick, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja050310n · Cited by 579
Cited by
Cu-Catalyzed Azide−Alkyne Cycloaddition
Meldal, M., & Tornøe, C. W. (2008) · Chemical Reviews · doi:10.1021/cr0783479 · Cited by 4,628
The growing applications of click chemistry
Moses, J. E., & Moorhouse, A. D. (2007) · Chem. Soc. Rev. · doi:10.1039/b613014n · Cited by 2,367
Lutz, J. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200604050 · Cited by 1,516
Marrying click chemistry with polymerization: expanding the scope of polymeric materials
Golas, P. L., & Matyjaszewski, K. (2010) · Chem. Soc. Rev. · doi:10.1039/b901978m · Cited by 863
Click Chemistry in Materials Science
Xi, W., Scott, T. F., Kloxin, C. J., & Bowman, C. N. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201302847 · Cited by 677
“Click”‐Chemistry in Polymer and Material Science: the Update
Binder, W. H. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800332 · Cited by 567
Johnson, J. A., Finn, M. G., Koberstein, J. T., & Turro, N. J. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800208 · Cited by 320
Metadata
- Authors
- Li, H., Cheng, F., Duft, A. M., & Adronov, A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-09-23
- Volume
- 127
- Issue
- 41
- Pages
- 14518-14524
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2056947115
- Cited by
- 432
- References
- 3
- FWCI
- 16.73
- Type
- journal article
- Language
- en
- Open access
- closed
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