The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Engineering Pt in Ceria for a Maximum Metal−Support Interaction in Catalysis
Abstract
Conventional supported metal catalysts are metal nanoparticles deposited on high surface area oxide supports with a poorly defined metal-support interface. Typically, the traditionally prepared Pt/ceria catalyzes both methanation (H2/CO to CH4) and water-gas shift (CO/H2O to CO2/H2) reactions. By using simple nanochemistry techniques, we show for the first time that Pt or PtAu metal can be created inside each CeO2 particle with tailored dimensions. The encapsulated metal is shown to interact with the thin CeO2 overlayer in each single particle in an optimum geometry to create a unique interface, giving high activity and excellent selectivity for the water-gas shift reaction, but is totally inert for methanation. Thus, this work clearly demonstrates the significance of nanoengineering of a single catalyst particle by a bottom-up construction approach in modern catalyst design which could enable exploitation of catalyst site differentiation, leading to new catalytic properties.
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Cites
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Tauster, S. J., Fung, S. C., & Garten, R. L. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00469a029 · Cited by 3,188
Cited by
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
Montini, T., Melchionna, M., Monai, M., & Fornasiero, P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00603 · Cited by 2,766
Yang, S., Kim, J., Tak, Y. J., Soon, A., & Lee, H. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201509241 · Cited by 899
Fang, B., Chaudhari, N. K., Kim, M.-S., Kim, J. H., & Yu, J.-S. (2009) · Journal of the American Chemical Society · doi:10.1021/ja905749e · Cited by 311
Bui, H. T., Weon, S., Bae, J. W., Kim, E.-J., Kim, B., Ahn, Y.-Y., Kim, K., Lee, H., & Kim, W. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.123976 · Cited by 134
Fang, B., Kim, M.-S., Kim, J. H., Song, M. Y., Wang, Y.-J., Wang, H., Wilkinson, D. P., & Yu, J.-S. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm10847f · Cited by 89
Metadata
- Authors
- Yeung, C. M. Y., Yu, K. M. K., Fu, Q. J., Thompsett, D., Petch, M. I., & Tsang, S. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-12-01
- Volume
- 127
- Issue
- 51
- Pages
- 18010-18011
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2084731471
- Cited by
- 222
- References
- 1
- FWCI
- 4.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yeung, C. M. Y., Yu, K. M. K., Fu, Q. J., Thompsett, D., Petch, M. I., & Tsang, S. C. (2005). Engineering Pt in Ceria for a Maximum Metal−Support Interaction in Catalysis. Journal of the American Chemical Society. https://doi.org/10.1021/ja056102c
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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