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Guest-Induced Asymmetry in a Metal−Organic Porous Solid with Reversible Single-Crystal-to-Single-Crystal Structural Transformation
Abstract
A metal-organic honeycomb-like 2D pillared-bilayer open framework has been constructed which shows dynamic sponge-like single-crystal-to-single-crystal transformation upon dehydration and rehydration. The dehydrated acentric nonporous phase transformed to the porous centric phase with the selective adsorbate concomitant with the structural transformation correlated with the single-crystal structure determination.
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks
Choi, H., & Suh, M. P. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200902836 · Cited by 389
Thermodynamics of Guest-Induced Structural Transitions in Hybrid Organic−Inorganic Frameworks
Coudert, F.-X., Jeffroy, M., Fuchs, A. H., Boutin, A., & Mellot-Draznieks, C. (2008) · Journal of the American Chemical Society · doi:10.1021/ja805129c · Cited by 337
Gating effect for gas adsorption in microporous materials—mechanisms and applications
Chen, K., Mousavi, S. H., Singh, R., Snurr, R. Q., Li, G., & Webley, P. A. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00822f · Cited by 133
Metadata
- Authors
- Maji, T. K., Mostafa, G., Matsuda, R., & Kitagawa, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-11-17
- Volume
- 127
- Issue
- 49
- Pages
- 17152-17153
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2046289100
- Cited by
- 330
- References
- 0
- FWCI
- 13.44
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Guest-Induced Asymmetry in a Metal−Organic Porous Solid with Reversible Single-Crystal-to-Single-Crystal Structural Transformation. https://app.cochat.ai/papers/10.1021/ja0561439
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- Maji, T. K., Mostafa, G., Matsuda, R., & Kitagawa, S. (2005). Guest-Induced Asymmetry in a Metal−Organic Porous Solid with Reversible Single-Crystal-to-Single-Crystal Structural Transformation. Journal of the American Chemical Society. https://doi.org/10.1021/ja0561439
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