The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.
Compositional Dependence of Negative Thermal Expansion in the Prussian Blue Analogues MIIPtIV(CN)6 (M = Mn, Fe, Co, Ni, Cu, Zn, Cd)
Abstract
The effect of M(II) substitution on the magnitude of the negative thermal expansion (NTE) behavior within a series of Prussian Blue analogues, M(II)Pt(IV)(CN)(6) for M(II) = Mn, Fe, Co, Ni, Cu, Zn, Cd, has been investigated using variable-temperature powder X-ray diffraction (100-400 K). The NTE behavior varies widely with M(II) substitution, from near zero thermal expansion in NiPt(CN)(6) (alpha = dl/l dT = -1.02(11) x 10(-)(6) K(-)(1)) up to a maximum in CdPt(CN)(6) (alpha = -10.02(11) x 10(-)(6) K(-)(1)). The trend in the magnitude of the NTE behavior, with increasing atomic number (Z) of the M(II) ion, follows the order Mn(II) > Fe(II) > Co(II) > Ni(II) < Cu(II) < Zn(II) < Cd(II), which correlates with the trends for M(II) cation size, the lattice parameter, and structural flexibility as indicated by the temperature-dependent structural refinements and Raman spectroscopy. Analysis of the temperature dependence of the average structures suggests that the differences in the thermal expansion are due principally to the different strengths of the metal-cyanide binding interaction and, accordingly, the different energies of transverse vibration of the cyanide bridge, with enhanced NTE behavior for more flexible lattices.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Two-dimensional detector software: From real detector to idealised image or two-theta scan
Hammersley, A. P., Svensson, S. O., Hanfland, M., Fitch, A. N., & Hausermann, D. (1996) · High Pressure Research · doi:10.1080/08957959608201408 · Cited by 4,674
Hoskins, B. F., & Robson, R. (1990) · Journal of the American Chemical Society · doi:10.1021/ja00160a038 · Cited by 1,933
Rapid-acquisition pair distribution function (RA-PDF) analysis
Chupas, P. J., Qiu, X., Hanson, J. C., Lee, P. L., Grey, C. P., & Billinge, S. J. L. (2003) · Journal of Applied Crystallography · doi:10.1107/s0021889803017564 · Cited by 575
Self-citationBarrera, G. D., Bruno, J. A. O., Barron, T. H. K., & Allan, N. L. (2005) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/17/4/r03 · Cited by 566
Herren, F., Fischer, P., Ludi, A., & Haelg, W. (1980) · Inorganic Chemistry · doi:10.1021/ic50206a032 · Cited by 562
Origin of the negative thermal expansion in and
Pryde, A. K. A., Hammonds, K. D., Dove, M. T., Heine, V., Gale, J. D., & Warren, M. C. (1996) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/8/50/023 · Cited by 274
Negative Thermal Expansion and Phase Transitions in the ZrV2-xPxO7 Series
Korthuis, V., Khosrovani, N., Sleight, A. W., Roberts, N., Dupree, R., & Warren, W. W. J. (1995) · Chemistry of Materials · doi:10.1021/cm00050a028 · Cited by 268
Homogeneous NMR Spectra in Inhomogeneous Fields
Vathyam, S., Lee, S., & Warren, W. S. (1996) · Science · doi:10.1126/science.272.5258.92 · Cited by 240
ISOTROPIC NEGATIVE THERMAL EXPANSION
Sleight, A. W. (1998) · Annual Review of Materials Science · doi:10.1146/annurev.matsci.28.1.29 · Cited by 232
Cited by
Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF3
Greve, B. K., Martin, K. L., Lee, P. L., Chupas, P. J., Chapman, K. W., & Wilkinson, A. P. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106711v · Cited by 494
Self-citationDove, M. T., & Fang, H. (2016) · Reports on Progress in Physics · doi:10.1088/0034-4885/79/6/066503 · Cited by 313
Nanoarchitectonics: A New Materials Horizon for Prussian Blue and Its Analogues
Azhar, A., Li, Y., Cai, Z., Zakaria, M. B., Masud, M. K., Hossain, M. S. A., Kim, J., Zhang, W., Na, J., Yamauchi, Y., et al. (2019) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20180368 · Cited by 267
Metadata
- Authors
- Chapman, K. W., Chupas, P. J., & Kepert, C. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-05-01
- Volume
- 128
- Issue
- 21
- Pages
- 7009-7014
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1987943437
- Cited by
- 272
- References
- 14
- FWCI
- 8.46
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Compositional Dependence of Negative Thermal Expansion in the Prussian Blue Analogues MIIPtIV(CN)6 (M = Mn, Fe, Co, Ni, Cu, Zn, Cd). https://app.cochat.ai/papers/10.1021/ja060916r
- The paper
- Chapman, K. W., Chupas, P. J., & Kepert, C. J. (2006). Compositional Dependence of Negative Thermal Expansion in the Prussian Blue Analogues MIIPtIV(CN)6 (M = Mn, Fe, Co, Ni, Cu, Zn, Cd). Journal of the American Chemical Society. https://doi.org/10.1021/ja060916r
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
