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Probing a Conjugated Polymer's Transfer of Organization-Dependent Properties from Solutions to Films
Abstract
The dynamic transfer of a conjugated polymer's organization-dependent properties from the solution state to the solid film state was probed by circularly polarized luminescence (CPL) and circular dichroism (CD) spectroscopy. Different supramolecular organizations within films and aggregate solutions of a chiral poly(p-phenylenevinylene) derivative led to opposite CPL and CD spectra. These dramatic property differences were controlled by regulating the polymer's self-assembly through solvent selection and film annealing. Therefore, different processing conditions can greatly affect the functional properties of conjugated polymer films employed in various optoelectronic applications.
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Citations
Cited by
Supramolecular Chirality in Self-Assembled Systems
Liu, M., Zhang, L., & Wang, T. (2015) · Chemical Reviews · doi:10.1021/cr500671p · Cited by 2,250
Pathway Complexity in π-Conjugated Materials
Korevaar, P. A., de Greef, T. F. A., & Meijer, E. W. (2014) · Chemistry of Materials · doi:10.1021/cm4021172 · Cited by 301
San Jose, B. A., Yan, J., & Akagi, K. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201404250 · Cited by 269
Metadata
- Authors
- Satrijo, A., Meskers, S. C. J., & Swager, T. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-06-22
- Volume
- 128
- Issue
- 28
- Pages
- 9030-9031
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2106108709
- Cited by
- 206
- References
- 0
- FWCI
- 3.79
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
