The DOI matches its Crossref record.
Luminescent Triarylborane-Functionalized Polystyrene: Synthesis, Photophysical Characterization, and Anion-Binding Studies
Abstract
A new class of highly fluorescent triarylborane polymers has been prepared from trimethylsilyl-substituted polystyrene via a modular approach that involves selective polymer modification reactions with organometallic reagents. The photophysical properties, environmental stability, and the Lewis acidity of the boron sites have been tailored through modifications in the substitution pattern on boron. The photophysical properties are indicative of electronic communication between the chromophores attached to polystyrene, which has been exploited for the efficient probing of fluoride and cyanide in the micromolar concentration range.
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Citations
Cited by
Recognition and sensing of fluoride anion
Cametti, M., & Rissanen, K. (2009) · Chemical Communications · doi:10.1039/b902069a · Cited by 654
Boron based anion receptors as sensors
Galbraith, E., & James, T. D. (2010) · Chemical Society Reviews · doi:10.1039/b926165f · Cited by 377
Kim, Y., & Gabbaï, F. P. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8091467 · Cited by 260
Metadata
- Authors
- Parab, K., Venkatasubbaiah, K., & Jäkle, F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-09-13
- Volume
- 128
- Issue
- 39
- Pages
- 12879-12885
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2063060519
- Cited by
- 314
- References
- 0
- FWCI
- 11.39
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.