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Oriented Growth of the Metal Organic Framework Cu3(BTC)2(H2O)3·x H2O Tunable with Functionalized Self-Assembled Monolayers
Abstract
The tunable oriented growth of thin films of the porous framework HKUST-1 (Cu 3 (C 9 H 3 O 6 ) 2 (H 2 O) 3 · x H 2 O) on different functionalized self-assembled monolayers (SAMs) is demonstrated. Films grown on carboxylate-terminated self-assembled monolayers are highly oriented along the [100] direction, while alcohol-terminated surfaces induce a completely different orientation along the [111] direction. Homogeneous but less oriented thin films are also obtained on methyl-terminated SAMs. A combination of X-ray diffraction and scanning electron microscopy was used to document the film growth on the self-assembled monolayers and to follow the morphological evolution of the crystalline phases.
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Metadata
- Authors
- Biemmi, E., Scherb, C., & Bein, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-06-07
- Volume
- 129
- Issue
- 26
- Pages
- 8054-8055
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1974590631
- Cited by
- 535
- References
- 0
- FWCI
- 23.95
- Type
- journal article
- Language
- en
- Open access
- closed
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