The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Constructing Hierarchical Spheres from Large Ultrathin Anatase TiO2 Nanosheets with Nearly 100% Exposed (001) Facets for Fast Reversible Lithium Storage
Abstract
Synthesis of nanocrystals with exposed high-energy facets is a well-known challenge in many fields of science and technology. The higher reactivity of these facets simultaneously makes them desirable catalysts for sluggish chemical reactions and leads to their small populations in an equilibrated crystal. Using anatase TiO(2) as an example, we demonstrate a facile approach for creating high-surface-area stable nanosheets comprising nearly 100% exposed (001) facets. Our approach relies on spontaneous assembly of the nanosheets into three-dimensional hierarchical spheres, which stabilizes them from collapse. We show that the high surface density of exposed TiO(2) (001) facets leads to fast lithium insertion/deinsertion processes in batteries that mimic features seen in high-power electrochemical capacitors.
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Cites
Colloidal nanocrystal synthesis and the organic–inorganic interface
Yin, Y., & Alivisatos, A. P. (2005) · Nature · doi:10.1038/nature04165 · Cited by 3,273
Tian, N., Zhou, Z.-Y., Sun, S.-G., Ding, Y., & Wang, Z. L. (2007) · Science · doi:10.1126/science.1140484 · Cited by 3,073
Morphological Control of Catalytically Active Platinum Nanocrystals
Lee, H., Habas, S. E., Kweskin, S., Butcher, D., Somorjai, G. A., & Yang, P. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200603068 · Cited by 659
Cited by
TiO2 photocatalysis: Design and applications
Nakata, K., & Fujishima, A. (2012) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2012.06.001 · Cited by 3,651
Ajmal, A., Majeed, I., Malik, R. N., Idriss, H., & Nadeem, M. A. (2014) · RSC Adv. · doi:10.1039/c4ra06658h · Cited by 1,485
Titanium Dioxide Crystals with Tailored Facets
Liu, G., Yang, H. G., Pan, J., Yang, Y. Q., Lu, G. Q. (., & Cheng, H.-M. (2014) · Chemical Reviews · doi:10.1021/cr400621z · Cited by 1,084
Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries
Wu, H. B., Chen, J. S., Hng, H. H., & Wen (David) Lou, X. (2012) · Nanoscale · doi:10.1039/c2nr11966h · Cited by 1,082
Self-citationTwo‐Dimensional Metal Oxide Nanomaterials for Next‐Generation Rechargeable Batteries
Mei, J., Liao, T., Kou, L., & Sun, Z. (2017) · Advanced Materials · doi:10.1002/adma.201700176 · Cited by 459
Metadata
- Authors
- Chen, J. S., Tan, Y. L., Li, C. M., Cheah, Y. L., Luan, D., Madhavi, S., Boey, F. Y. C., Archer, L. A., & Lou, X. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-04-14
- Volume
- 132
- Issue
- 17
- Pages
- 6124-6130
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1981995376
- Cited by
- 1,243
- References
- 3
- FWCI
- 93.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, J. S., Tan, Y. L., Li, C. M., Cheah, Y. L., Luan, D., Madhavi, S., Boey, F. Y. C., Archer, L. A., & Lou, X. W. (2010). Constructing Hierarchical Spheres from Large Ultrathin Anatase TiO2 Nanosheets with Nearly 100% Exposed (001) Facets for Fast Reversible Lithium Storage. Journal of the American Chemical Society. https://doi.org/10.1021/ja100102y
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