Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-Oxidation Activity
Abstract
The shapes of noble metal nanocrystals (NCs) are usually defined by polyhedra that are enclosed by {111} and {100} facets, such as cubes, tetrahedra, and octahedra. Platinum NCs of unusual tetrahexahedral (THH) shape were prepared at high yield by an electrochemical treatment of Pt nanospheres supported on glassy carbon by a square-wave potential. The single-crystal THH NC is enclosed by 24 high-index facets such as {730}, {210}, and/or {520} surfaces that have a large density of atomic steps and dangling bonds. These high-energy surfaces are stable thermally (to 800°C) and chemically and exhibit much enhanced (up to 400%) catalytic activity for equivalent Pt surface areas for electro-oxidation of small organic fuels such as formic acid and ethanol.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
THH Pt nanocrystals are bounded by 24 facets of high-index planes (730) and vicinal planes such as (210) and (310).
“The tetrahexahedral (THH) shape nanocrystal is bounded by 24 facets of high-index planes (730) and vicinal planes such as (210) and (310).57”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [57]
The dominant facets of the THH Pt nanocrystals are (730) with contributions from (210), (310), and (520).
“Therefore, the dominant facets of the THH Pt nanocrystals are (730) with contributions from ( 210), (310), and (520).”
From A comprehensive review of Pt electrocatalysts for the oxygen reduction reaction: Nanostructure, activity, mechanism and carbon support in PEM fuel cells (2017) · cites this paper as [57]
Cites
Shape-Controlled Synthesis of Gold and Silver Nanoparticles
Sun, Y., & Xia, Y. (2002) · Science · doi:10.1126/science.1077229 · Cited by 6,509 · see citing works
Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421 · see citing works
Larminie, J., & Dicks, A. L. (2003) · Wiley eBooks · doi:10.1002/9781118878330 · Cited by 4,021 · see citing works
Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles
Ahmadi, T. S., Wang, Z. L., Green, T. C., Henglein, A., & El-Sayed, M. A. (1996) · Science · doi:10.1126/science.272.5270.1924 · Cited by 2,373 · see citing works
Self-citationStabilization of Platinum Oxygen-Reduction Electrocatalysts Using Gold Clusters
Zhang, J., Sasaki, K., Sutter, E., & Adzic, R. R. (2007) · Science · doi:10.1126/science.1134569 · Cited by 1,779 · see citing works
Hydrogen Sensors and Switches from Electrodeposited Palladium Mesowire Arrays
Favier, F., Walter, E. C., Zach, M. P., Benter, T., & Penner, R. M. (2001) · Science · doi:10.1126/science.1063189 · Cited by 1,384 · see citing works
Shape-Dependent Catalytic Activity of Platinum Nanoparticles in Colloidal Solution
Narayanan, R., & El‐Sayed, M. A. (2004) · Nano Letters · doi:10.1021/nl0495256 · Cited by 1,208 · see citing works
Kim, F., Connor, S. T., Song, H., Kuykendall, T., & Yang, P. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200454216 · Cited by 980 · see citing works
Heck, R. M., & Farrauto, R. J. (2001) · Applied Catalysis A General · doi:10.1016/s0926-860x(01)00818-3 · Cited by 682 · see citing works
Catalysis and Electrocatalysis at Nanoparticle Surfaces
Więckowski, A., Savinova, E. R., & Vayenas, C. G. (2003) · CRC Press eBooks · doi:10.1201/9780203912713 · Cited by 559 · see citing works
Pt Nanocrystals: Shape Control and Langmuir−Blodgett Monolayer Formation
Song, H., Kim, F., Connor, S., Somorjai, G. A., & Yang, P. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0464775 · Cited by 544 · see citing works
Mechanism of catalysis of hydrocarbon reactions by platinum surfaces
Somorjai, G. A., & Blakely, D. W. (1975) · Nature · doi:10.1038/258580a0 · Cited by 357 · see citing works
The Growth of Uniform Colloidal Dispersions
Reiss, H. (1951) · The Journal of Chemical Physics · doi:10.1063/1.1748251 · Cited by 336 · see citing works
Xiong, Y., McLellan, J. M., Yin, Y., & Younan Xia, A. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200604032 · Cited by 276 · see citing works
Blakely, D. W., & Somorjai, G. A. (1977) · Surface Science · doi:10.1016/0039-6028(77)90457-5 · Cited by 246 · see citing works
Vidal‐Iglesias, F. J., Solla‐Gullón, J., Rodríguez, P., Herrero, E., Montiel, V., Feliu, J. M., & Aldaz, A. (2004) · Electrochemistry Communications · doi:10.1016/j.elecom.2004.08.010 · Cited by 234 · see citing works
Buckley, H. E., & Walker, A. C. (1951) · American Journal of Physics · doi:10.1119/1.1933020 · Cited by 146 · see citing works
Thin film deposition: fundamentals and modeling
Gilmer, G. H., Huang, H., & Roland, C. (1998) · Computational Materials Science · doi:10.1016/s0927-0256(98)00022-6 · Cited by 131 · see citing works
Sun, S., Chen, A., Huang, T., Li, J.-B., & Tian, Z.-W. (1992) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(92)80299-j · Cited by 108 · see citing works
Self-citationShape‐Controlled Growth of Micrometer‐Sized Gold Crystals by a Slow Reduction Method
Liu, X., Wu, N., Wunsch, B. H., Barsotti, R. J., & Stellacci, F. (2006) · Small · doi:10.1002/smll.200600219 · Cited by 101 · see citing works
Visintin, A., Canullo, J. C., Triaca, W. E., & Arvia, A. J. (1988) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(88)80270-5 · Cited by 80 · see citing works
Furuya, N., & Shibata, M. (1999) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(99)00077-7 · Cited by 67 · see citing works
Nitric oxide decomposition on Pt(410)
Banholzer, W. F., & Masel, R. I. (1984) · Journal of Catalysis · doi:10.1016/0021-9517(84)90116-7 · Cited by 65 · see citing works
Recognition and separation of discrete objects within complex 3D voxelized structures
Proussevitch, A. A., & Sahagian, D. L. (2001) · Computers & Geosciences · doi:10.1016/s0098-3004(00)00141-2 · Cited by 62 · see citing works
Hoshi, N., Kawatani, S., Kudo, M., & Hori, Y. (1999) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(98)00476-8 · Cited by 42 · see citing works
Gong, H., Sun, S., Chen, Y.-J., & Chen, S. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0375822 · Cited by 32 · see citing works
Self-citationTripković, A. V., & Adžić, R. R. (1986) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(86)90246-9 · Cited by 31 · see citing works
Egli, W. A., Visintin, A., Triaca, W. E., & Arvia, A. J. (1993) · Applied Surface Science · doi:10.1016/0169-4332(93)90240-c · Cited by 23 · see citing works
Oxygen-induced step-edge faceting; a precursor to (410) planar faceting of Cu(100) vicinal surfaces
Knight, P., Driver, S. M., & Woodruff, D. P. (1996) · Chemical Physics Letters · doi:10.1016/0009-2614(96)00753-1 · Cited by 14 · see citing works
Sun, S., Yang, D., Wu, S., Ociepa, J., & Lipkowski, J. (1993) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(93)80174-g · Cited by 11 · see citing works
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702 · see citing works
Anatase TiO2 single crystals with a large percentage of reactive facets
Yang, H. G., Sun, C., Qiao, S., Zou, J., Liu, G., Smith, S. C., Cheng, H., & Lu, G. Q. (2008) · Nature · doi:10.1038/nature06964 · Cited by 4,104 · see citing works
Pd-Pt Bimetallic Nanodendrites with High Activity for Oxygen Reduction
Lim, B., Jiang, M., Camargo, P. H. C., Cho, E. C., Tao, J., Lu, X., Zhu, Y., & Younan Xia, A. (2009) · Science · doi:10.1126/science.1170377 · Cited by 2,983 · see citing works
Shape Control of Colloidal Metal Nanocrystals
Tao, A. R., Habas, S., & Yang, P. (2008) · Small · doi:10.1002/smll.200701295 · Cited by 2,408 · see citing works
Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices
Guo, Y., Hu, J., & Wan, L. (2008) · Advanced Materials · doi:10.1002/adma.200800627 · Cited by 2,224 · see citing works
Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction
Nie, Y., Li, L., & Wei, Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00484a · Cited by 2,156 · see citing works
Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures
Christopher, P., Xin, H., & Linic, S. (2011) · Nature Chemistry · doi:10.1038/nchem.1032 · Cited by 1,999 · see citing works
Li, H., Shang, J., Ai, Z., & Zhang, L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03105 · Cited by 1,782 · see citing works
Han, X., Kuang, Q., Jin, M., Xie, Z., & Zheng, L. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8092373 · Cited by 1,632 · see citing works
AFLOW: An automatic framework for high-throughput materials discovery
Stefano Curtarolo, A., Setyawan, W., Hart, G. L. W., Jahnátek, M., Chepulskii, R. V., Taylor, R. H., Wang, S., Junkai Xue, A., Yang, K., Levy, O., et al. (2012) · Computational Materials Science · doi:10.1016/j.commatsci.2012.02.005 · Cited by 1,521 · see citing works
Nanomaterial by Sol‐Gel Method: Synthesis and Application
Bokov, D. O., Jalil, A. T., Chupradit, S., Suksatan, W., Ansari, M. J., Shewael, I. H., Valiev, G. H., & Kianfar, E. (2021) · Advances in Materials Science and Engineering · doi:10.1155/2021/5102014 · Cited by 1,512 · see citing works
RetractedThermally stable Pt/mesoporous silica core–shell nanocatalysts for high-temperature reactions
Joo, S. H., Park, J. Y., Tsung, C., Yamada, Y., Yang, P., & Somorjai, G. A. (2008) · Nature Materials · doi:10.1038/nmat2329 · Cited by 1,464 · see citing works
Oxygen electrocatalysts in metal–air batteries: from aqueous to nonaqueous electrolytes
Wang, Z., Xu, D., Xu, J., & Zhang, X. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60248f · Cited by 1,452 · see citing works
Self-citationPlatinum-Based Nanostructured Materials: Synthesis, Properties, and Applications
Chen, A., & Holt-Hindle, P. (2010) · Chemical Reviews · doi:10.1021/cr9003902 · Cited by 1,390 · see citing works
One-dimensional ZnO nanostructures: Solution growth and functional properties
Xu, S., & Wang, Z. L. (2011) · Nano Research · doi:10.1007/s12274-011-0160-7 · Cited by 1,362 · see citing works
Self-citationSolvothermal Synthesis and Photoreactivity of Anatase TiO 2 Nanosheets with Dominant {001} Facets
Yang, H. G., Liu, G., Qiao, S., Sun, C., Jin, Y. G., Smith, S. C., Zou, J., Cheng, H., & Lu, G. Q. (2009) · Journal of the American Chemical Society · doi:10.1021/ja808790p · Cited by 1,303 · see citing works
Wang, H., Lee, H.-W., Deng, Y., Lu, Z., Hsu, P.-C., Liu, Y., Lin, D., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8261 · Cited by 1,257 · see citing works
Reier, T., Nong, H. N., Teschner, D., Schlögl, R., & Strasser, P. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601275 · Cited by 1,253 · see citing works
Chen, J. S., Tan, Y., Li, C. M., Cheah, Y. L., Luan, D., Srinivasan, M., Boey, F. Y. C., Archer, L. A., & Lou, X. W. (2010) · Journal of the American Chemical Society · doi:10.1021/ja100102y · Cited by 1,243 · see citing works
On the True Photoreactivity Order of {001}, {010}, and {101} Facets of Anatase TiO2 Crystals
Pan, J., Liu, G., Lu, G. Q., & Cheng, H. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201006057 · Cited by 1,239 · see citing works
Cuenya, B. R. (2010) · Thin Solid Films · doi:10.1016/j.tsf.2010.01.018 · Cited by 1,186 · see citing works
Guo, S., Dong, S., & Wang, E. (2009) · ACS Nano · doi:10.1021/nn9014483 · Cited by 1,168 · see citing works
Nanostructured Pt-alloy electrocatalysts for PEM fuel cell oxygen reduction reaction
Bing, Y., Liu, H., Zhang, L., Ghosh, D., & Zhang, J. (2010) · Chemical Society Reviews · doi:10.1039/b912552c · Cited by 1,154 · see citing works
Metal/Semiconductor Hybrid Nanostructures for Plasmon‐Enhanced Applications
Jiang, R., Li, B., Fang, C., & Wang, J. (2014) · Advanced Materials · doi:10.1002/adma.201400203 · Cited by 1,154 · see citing works
Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries
Lu, Y., & Chen, W. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15325d · Cited by 1,152 · see citing works
Titanium Dioxide Crystals with Tailored Facets
Liu, G., Yang, H. G., Pan, J., Yang, Y. Q., Lu, G. Q., & Cheng, H. (2014) · Chemical Reviews · doi:10.1021/cr400621z · Cited by 1,091 · see citing works
Peng, Z., & Yang, H. (2009) · Nano Today · doi:10.1016/j.nantod.2008.10.010 · Cited by 1,085 · see citing works
Platinum-Based Oxygen Reduction Electrocatalysts
Wu, J., & Yang, H. (2013) · Accounts of Chemical Research · doi:10.1021/ar300359w · Cited by 1,050 · see citing works
Liu, X., Iocozzia, J., Wang, Y., Cui, X., Chen, Y., Zhao, S., Li, Z., & Lin, Z. (2016) · Energy & Environmental Science · doi:10.1039/c6ee02265k · Cited by 1,034 · see citing works
Properties and Applications of Colloidal Nonspherical Noble Metal Nanoparticles
Sau, T. K., Rogach, A. L., Jäckel, F., Klar, T. A., & Feldmann, J. (2010) · Advanced Materials · doi:10.1002/adma.200902557 · Cited by 1,020 · see citing works
Two-Dimensional Metal Nanomaterials: Synthesis, Properties, and Applications
Chen, Y., Fan, Z., Zhang, Z., Niu, W., Li, C., Yang, N., Chen, B., & Zhang, H. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00727 · Cited by 1,000 · see citing works
Tuning Nanoparticle Catalysis for the Oxygen Reduction Reaction
Guo, S., Zhang, S., & Sun, S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201207186 · Cited by 994 · see citing works
Self-citationLiu, G., Yu, J. C., Lu, G. Q., & Cheng, H. (2011) · Chemical Communications · doi:10.1039/c1cc10665a · Cited by 989 · see citing works
Graphene-Supported Nanoelectrocatalysts for Fuel Cells: Synthesis, Properties, and Applications
Liu, M., Zhang, R., & Chen, W. (2014) · Chemical Reviews · doi:10.1021/cr400523y · Cited by 982 · see citing works
Shape-Controlled Synthesis of Colloidal Metal Nanocrystals: Thermodynamic versus Kinetic Products
Younan Xia, A., Xia, X., & Peng, H. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04641 · Cited by 973 · see citing works
Hu, L., Peng, Q., & Li, Y. (2008) · Journal of the American Chemical Society · doi:10.1021/ja806400e · Cited by 944 · see citing works
Bose, S., Kuila, T., Nguyen, T. X. H., Kim, N. H., Lau, K.-T., & Lee, J. H. (2011) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.01.003 · Cited by 934 · see citing works
Can Boron and Nitrogen Co-doping Improve Oxygen Reduction Reaction Activity of Carbon Nanotubes?
Zhao, Y. F., Yang, L., Chen, S., Wang, X., Ma, Y., Wu, Q., Jiang, Y., Qian, W., & Hu, Z. (2013) · Journal of the American Chemical Society · doi:10.1021/ja310566z · Cited by 929 · see citing works
Sui, S., Wang, X., Zhou, X., Su, Y., Riffat, S., & Liu, C.-J. (2017) · Journal of Materials Chemistry A · doi:10.1039/c6ta08580f · Cited by 916 · see citing works
Nonspherical Noble Metal Nanoparticles: Colloid‐Chemical Synthesis and Morphology Control
Sau, T. K., & Rogach, A. L. (2009) · Advanced Materials · doi:10.1002/adma.200901271 · Cited by 911 · see citing works
Atomic origins of the high catalytic activity of nanoporous gold
Fujita, T., Guan, P., McKenna, K. P., Lang, X., Hirata, A., Zhang, L., Tokunaga, T., Arai, S., Yamamoto, Y., Tanaka, N., et al. (2012) · Nature Materials · doi:10.1038/nmat3391 · Cited by 905 · see citing works
Structure and activity of nanozymes: Inspirations for de novo design of nanozymes
Wang, Z., Zhang, R., Yan, X., & Fan, K. (2020) · Materials Today · doi:10.1016/j.mattod.2020.08.020 · Cited by 900 · see citing works
Self-citationNanomaterials of high surface energy with exceptional properties in catalysis and energy storage
Zhou, Z., Tian, N., Li, J., Broadwell, I., & Sun, S. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00176g · Cited by 885 · see citing works
Self-citationNanostructured electrocatalysts with tunable activity and selectivity
Mistry, H., Varela, A. S., Kühl, S., Strasser, P., & Cuenya, B. R. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.9 · Cited by 867 · see citing works
Shape-controlled synthesis of platinum nanocrystals for catalytic and electrocatalytic applications
Chen, J., Lim, B., Lee, E. P., & Xia, Y. (2009) · Nano Today · doi:10.1016/j.nantod.2008.09.002 · Cited by 852 · see citing works
Parashar, M., Shukla, V. K., & Singh, R. (2020) · Journal of Materials Science Materials in Electronics · doi:10.1007/s10854-020-02994-8 · Cited by 840 · see citing works
Catalysis Based on Nanocrystals with Well‐Defined Facets
Zhou, K., & Li, Y. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201102619 · Cited by 820 · see citing works
Noble metal nanoparticles for water purification: A critical review
Pradeep, T., & Anshup (2009) · Thin Solid Films · doi:10.1016/j.tsf.2009.03.195 · Cited by 810 · see citing works
Guo, S., & Wang, E. (2011) · Nano Today · doi:10.1016/j.nantod.2011.04.007 · Cited by 799 · see citing works
Seed‐Mediated Growth of Colloidal Metal Nanocrystals
Younan Xia, A., Gilroy, K. D., Peng, H., & Xia, X. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604731 · Cited by 799 · see citing works
Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt<sub>3</sub>Ni Nanopolyhedra
Zhang, J., Yang, H., Fang, J., & Zou, S. (2010) · Nano Letters · doi:10.1021/nl903717z · Cited by 788 · see citing works
Colloidal Hybrid Nanostructures: A New Type of Functional Materials
Costi, R., Saunders, A. E., & Banin, U. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200906010 · Cited by 787 · see citing works
Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?
Trovarelli, A., & Llorca, J. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01246 · Cited by 787 · see citing works
Preparation of Inorganic Materials Using Ionic Liquids
Ma, Z., Yu, J., & Dai, S. (2009) · Advanced Materials · doi:10.1002/adma.200900603 · Cited by 777 · see citing works
Forging Colloidal Nanostructures via Cation Exchange Reactions
Trizio, L. D., & Manna, L. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00739 · Cited by 772 · see citing works
Cao, S., Tao, F. F., Tang, Y., Li, Y., & Yu, J. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00094k · Cited by 759 · see citing works
Rong, S., Zhang, P., Liu, F., & Yang, Y. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00456 · Cited by 740 · see citing works
Yan, K., Long, M., Zhang, T., Wei, Z., Chen, H., Yang, S., & Xu, J. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00321 · Cited by 737 · see citing works
Surface engineering of hierarchical platinum-cobalt nanowires for efficient electrocatalysis
Bu, L., Guo, S., Zhang, X., Shen, X., Su, D., Lü, G., Zhu, X., Yao, J., Guo, J., & Huang, X. (2016) · Nature Communications · doi:10.1038/ncomms11850 · Cited by 737 · see citing works
Real-Time Imaging of Pt 3 Fe Nanorod Growth in Solution
Liao, H., Cui, L., Whitelam, S., & Zheng, H. (2012) · Science · doi:10.1126/science.1219185 · Cited by 733 · see citing works
Noble-Metal Nanocrystals with Controlled Shapes for Catalytic and Electrocatalytic Applications
Shi, Y., Lyu, Z., Zhao, M., Chen, R., Nguyen, Q. N., & Younan Xia, A. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00454 · Cited by 732 · see citing works
Li, Z., Chen, Y., Ji, S., Tang, Y., Chen, W., Li, A., Zhao, J., Xiong, Y., Wu, Y. S., Gong, Y., et al. (2020) · Nature Chemistry · doi:10.1038/s41557-020-0473-9 · Cited by 723 · see citing works
Carbon‐Supported Single Atom Catalysts for Electrochemical Energy Conversion and Storage
Peng, Y., Lu, B., & Chen, S. W. (2018) · Advanced Materials · doi:10.1002/adma.201801995 · Cited by 716 · see citing works
Defining Rules for the Shape Evolution of Gold Nanoparticles
Langille, M. R., Personick, M. L., Zhang, J., & Mirkin, C. A. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305245g · Cited by 709 · see citing works
Ling, T., Yan, D.-Y., Jiao, Y., Wang, H., Zheng, Y., Zheng, X. R., Mao, J., Du, X., Hu, Z., Jaroniec, M., et al. (2016) · Nature Communications · doi:10.1038/ncomms12876 · Cited by 674 · see citing works
Electrochemical biosensors: perspective on functional nanomaterials for on-site analysis
Cho, I., Kim, D. H., & Park, S. (2020) · Biomaterials Research · doi:10.1186/s40824-019-0181-y · Cited by 653 · see citing works
Core–Shell Noble‐Metal@Metal‐Organic‐Framework Nanoparticles with Highly Selective Sensing Property
He, L., Liu, Y., Liu, J., Xiong, Y., Zheng, J., Liu, Y., & Tang, Z. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209903 · Cited by 640 · see citing works
Nanostructured electrode materials for electrochemical energy storage and conversion
Manthiram, A., Murugan, A. V., Sarkar, A. B., & Muraliganth, T. (2008) · Energy & Environmental Science · doi:10.1039/b811802g · Cited by 639 · see citing works
Crabtree, R. (2012) · Chemical Reviews · doi:10.1021/cr2002905 · Cited by 545 · see citing works
The {001} facets-dependent high photoactivity of BiOCl nanosheets
Ye, L., Zan, L., Tian, L., Peng, T., & Zhang, J. J. (2011) · Chemical Communications · doi:10.1039/c1cc11015b · Cited by 615 · see citing works
Yang, B., Chen, Y., & Shi, J. (2019) · Advanced Materials · doi:10.1002/adma.201901778 · Cited by 604 · see citing works
Surface Coordination Chemistry of Atomically Dispersed Metal Catalysts
Qin, R., Liu, K., Wu, Q., & Zheng, N. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00094 · Cited by 597 · see citing works
Choi, S., Xie, S., Shao, M., Odell, J. H., Lü, N., Peng, H., Protsailo, L., Guerrero, S., Park, J., Xia, X., et al. (2013) · Nano Letters · doi:10.1021/nl401881z · Cited by 589 · see citing works
Hierarchical SnO 2 Nanostructures: Recent Advances in Design, Synthesis, and Applications
Wang, H., & Rogach, A. L. (2013) · Chemistry of Materials · doi:10.1021/cm4018248 · Cited by 583 · see citing works
High-Index Faceted Noble Metal Nanocrystals
Quan, Z., Wang, Y., & Fang, J. (2013) · Accounts of Chemical Research · doi:10.1021/ar200293n · Cited by 582 · see citing works
Tian, N., Zhou, Z., & Sun, S. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp804051e · Cited by 577 · see citing works
Self-citationDefect Engineering for Fuel‐Cell Electrocatalysts
Li, W., Wang, D., Zhang, Y., Li, T., Wang, T., Zou, Y., Wang, Y., Chen, R., & Wang, S. (2020) · Advanced Materials · doi:10.1002/adma.201907879 · Cited by 572 · see citing works
Synthesis of colloidal metal and metal alloy nanoparticles for electrochemical energy applications
You, H., Yang, S., Ding, B., & Yang, H. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35319a · Cited by 560 · see citing works
Concave Cubic Gold Nanocrystals with High-Index Facets
Zhang, J., Langille, M. R., Personick, M. L., Zhang, K., Li, S., & Mirkin, C. A. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106394k · Cited by 557 · see citing works
Intermetallic Nanocrystals: Syntheses and Catalytic Applications
Yan, Y., Du, J. S., Gilroy, K. D., Yang, D., Younan Xia, A., & Zhang, H. (2017) · Advanced Materials · doi:10.1002/adma.201605997 · Cited by 551 · see citing works
Design concept for electrocatalysts
Wang, Y., Zheng, X., & Wang, D. S. (2021) · Nano Research · doi:10.1007/s12274-021-3794-0 · Cited by 549 · see citing works
Icosahedral Platinum Alloy Nanocrystals with Enhanced Electrocatalytic Activities
Wu, J., Qi, L., You, H., Gross, A., Li, J., & Yang, H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303950v · Cited by 546 · see citing works
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X. M., Yan, Z. W., Potsi, G., Selhorst, R. C., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 545 · see citing works
Noble-Metal Based Random Alloy and Intermetallic Nanocrystals: Syntheses and Applications
Zhou, M. Y., Li, C., & Fang, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00436 · Cited by 537 · see citing works
Morphology-dependent nanocatalysts: Rod-shaped oxides
Li, Y., & Shen, W. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60296f · Cited by 532 · see citing works
Zhao, S., Yin, H., Du, L., He, L., Zhao, K., Chang, L., Yin, G., Zhao, H., Liu, S., & Tang, Z. (2014) · ACS Nano · doi:10.1021/nn505582e · Cited by 530 · see citing works
Wang, L., Nemoto, Y., & Yamauchi, Y. (2011) · Journal of the American Chemical Society · doi:10.1021/ja202655j · Cited by 524 · see citing works
Zhou, X., Liu, G., Yu, J., & Fan, W. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm31902k · Cited by 524 · see citing works
Pt-Based electrocatalysts with high atom utilization efficiency: from nanostructures to single atoms
Zhang, L., Doyle‐Davis, K., & Sun, X. A. (2018) · Energy & Environmental Science · doi:10.1039/c8ee02939c · Cited by 523 · see citing works
Truncated Octahedral Pt<sub>3</sub>Ni Oxygen Reduction Reaction Electrocatalysts
Wu, J., Zhang, J., Peng, Z., Yang, S., Wagner, F. T., & Yang, H. (2010) · Journal of the American Chemical Society · doi:10.1021/ja100571h · Cited by 520 · see citing works
Nanoparticles functionalised with reversible molecular and supramolecular switches
Klajn, R., Stoddart, J. F., & Grzybowski, B. A. (2010) · Chemical Society Reviews · doi:10.1039/b920377j · Cited by 517 · see citing works
Persson, K. A., Waldwick, B. L., Lazić, P., & Ceder, G. (2012) · Physical Review B · doi:10.1103/physrevb.85.235438 · Cited by 516 · see citing works
Amine-Assisted Synthesis of Concave Polyhedral Platinum Nanocrystals Having {411} High-Index Facets
Huang, X., Zhao, Z., Fan, J., Tan, Y., & Zheng, N. (2011) · Journal of the American Chemical Society · doi:10.1021/ja1117528 · Cited by 513 · see citing works
Facet development during platinum nanocube growth
Liao, H., Zherebetskyy, D., Xin, H. L., Czarnik, C., Ercius, P. A., Elmlund, H., Pan, M., Wang, L.-W., & Zheng, H. (2014) · Science · doi:10.1126/science.1253149 · Cited by 513 · see citing works
Furukawa, S., & Komatsu, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02603 · Cited by 512 · see citing works
Molecular Factors of Catalytic Selectivity
Somorjai, G. A., & Park, J. Y. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803181 · Cited by 506 · see citing works
Wang, Y., Zou, S., & Cai, W. (2015) · Catalysts · doi:10.3390/catal5031507 · Cited by 505 · see citing works
Xie, S., Choi, S., Lü, N., Roling, L. T., Herron, J. A., Zhang, L., Park, J., Wang, J., Kim, M. J., Xie, Z., et al. (2014) · Nano Letters · doi:10.1021/nl501205j · Cited by 504 · see citing works
Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes
Ji, X., Lee, K. T., Holden, R., Zhang, L., Zhang, J., Botton, G. A., Couillard, M., & Nazar, L. F. (2010) · Nature Chemistry · doi:10.1038/nchem.553 · Cited by 500 · see citing works
Wang, H.-F., & Liu, Z. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801648h · Cited by 497 · see citing works
- Authors
- Tian, N., Zhou, Z.-Y., Sun, S.-G., Ding, Y., & Wang, Z. L.
- Affiliations
- Georgia Institute of Technology (US)
- Corresponding author
- Sun, Shi-Gang
- Wang, Zhong Lin
- Venue
- Science
- Published
- 2007-05-04
- Volume
- 316
- Issue
- 5825
- Pages
- 732-735
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2061820211
- Cited by
- 3,073
- References
- 30
- Citations by year
- 2026: 35 · 2025: 78 · 2024: 91 · 2023: 85 · 2022: 122 · 2021: 134 · 2020: 123 · 2019: 153 · 2018: 170 · 2017: 176 · 2016: 198 · 2015: 233 · 2014: 251 · 2013: 267 · 2012: 246
- FWCI
- 105.43
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Chemistry › Organic Chemistry › Nanomaterials for catalytic reactions
- Keywords
- platinum nanocrystals, high-index facets, electrochemical oxidation, formic acid oxidation, ethanol oxidation, electrocatalysis, nanocrystal synthesis, single-crystal nanocrystals
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review