The DOI matches its Crossref record.
High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes
Abstract
A polyquinoxaline-based helical polymer ligand bearing both helical-sense-determining chiral side chains and coordinating diarylphosphino side chains exhibits solvent-dependent formation of P- or M-helical structures, with which either the S- or R-hydrosilylation product was obtained with high (>93% enantiomeric excess) enantioselectivities.
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Citations
Cited by
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Funes-Maldonado, M., Sieng, B., & Amedjkouh, M. (2016) · Organic Letters · doi:10.1021/acs.orglett.6b00742 · Cited by 20
Metadata
- Authors
- Yamamoto, T., Yamada, T., Nagata, Y., & Suginome, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-05-20
- Volume
- 132
- Issue
- 23
- Pages
- 7899-7901
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2034490711
- Cited by
- 266
- References
- 0
- FWCI
- 10.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes. https://app.cochat.ai/papers/10.1021/ja102428q
- The paper
- Yamamoto, T., Yamada, T., Nagata, Y., & Suginome, M. (2010). High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes. Journal of the American Chemical Society. https://doi.org/10.1021/ja102428q
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
