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Top-Down Fabrication of α-Fe2O3 Single-Crystal Nanodiscs and Microparticles with Tunable Porosity for Largely Improved Lithium Storage Properties
Abstract
In this work, we report a facile top-down approach to fabricate uniform single-crystal α-Fe(2)O(3) nanodiscs via selective oxalic acid etching. Phosphate ions are employed as a capping agent to control the etching to along the [001] direction. We also show that α-Fe(2)O(3) melon-like microparticles with contrasting textural properties can be generated using the same approach. The etched particles exhibit a much larger total pore volume and average pore size compared to the pristine ones, thus serving as the possible origin for their greatly enhanced capacity retention when tested as potential anode materials for lithium-ion batteries.
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Cites
Ultra-large-scale syntheses of monodisperse nanocrystals
Park, J., An, K., Hwang, Y., Park, J.-G., Noh, H.-J., Kim, J.-Y., Park, J.-H., Hwang, N.-M., & Hyeon, T. (2004) · Nature Materials · doi:10.1038/nmat1251 · Cited by 4,076
Cited by
Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries
Wu, H. B., Chen, J. S., Hng, H. H., & Wen (David) Lou, X. (2012) · Nanoscale · doi:10.1039/c2nr11966h · Cited by 1,082
Self-citationHierarchical α-Fe2O3/NiO Composites with a Hollow Structure for a Gas Sensor
Wang, C., Cheng, X., Zhou, X., Sun, P., Hu, X., Shimanoe, K., Lu, G., & Yamazoe, N. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am501063z · Cited by 283
Synthesis, Properties, and Applications of Iron Oxides: Versatility and Challenges
Busti, N. D., Parra, R., & Sousa Góes, M. (2021) · Engineering Materials · doi:10.1007/978-3-030-62226-8_13 · Cited by 9
Metadata
- Authors
- Chen, J. S., Zhu, T., Yang, X. H., Yang, H. G., & Lou, X. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-07
- Volume
- 132
- Issue
- 38
- Pages
- 13162-13164
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2020744329
- Cited by
- 369
- References
- 1
- FWCI
- 33.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, J. S., Zhu, T., Yang, X. H., Yang, H. G., & Lou, X. W. (2010). Top-Down Fabrication of α-Fe2O3 Single-Crystal Nanodiscs and Microparticles with Tunable Porosity for Largely Improved Lithium Storage Properties. Journal of the American Chemical Society. https://doi.org/10.1021/ja1060438
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