The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Catalytic C−O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers
Open accessAbstract
A ruthenium-catalyzed, redox neutral C-O bond cleavage of 2-aryloxy-1-arylethanols was developed that yields cleavage products in 62-98% isolated yield. This reaction is applicable to breaking the key ethereal bond found in lignin-related polymers. The bond transformation proceeds by a tandem dehydrogenation/reductive ether cleavage. Initial mechanistic investigations indicate that the ether cleavage is most likely an organometallic C-O activation. A catalytic depolymerization of a lignin-related polymer quantitatively yields the corresponding monomer with no added reagent.
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Cites
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals
Zakzeski, J., Bruijnincx, P. C. A., Jongerius, A. L., & Weckhuysen, B. M. (2010) · Chemical Reviews · doi:10.1021/cr900354u · Cited by 4,468
Ohlrogge, J., Allen, D., Berguson, B., DellaPenna, D., Shachar-Hill, Y., & Stymne, S. (2009) · Science · doi:10.1126/science.1171740 · Cited by 167
Ibarra, D., Chávez, M. I., Rencoret, J., Del Río, J. C., Gutiérrez, A., Romero, J., Camarero, S., Martínez, M. J., Jiménez-Barbero, J., & Martínez, A. T. (2007) · Journal of Agricultural and Food Chemistry · doi:10.1021/jf063728t · Cited by 139
Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Sturgeon, M. R., Kim, S., Lawrence, K., Paton, R. S., Chmely, S. C., Nimlos, M., Foust, T. D., & Beckham, G. T. (2014) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc400384w · Cited by 414
Lu, X., & Gu, X. (2022) · Biotechnology for Biofuels and Bioproducts · doi:10.1186/s13068-022-02203-0 · Cited by 354
Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals
Deuss, P. J., Barta, K., & de Vries, J. G. (2014) · Catal. Sci. Technol. · doi:10.1039/c3cy01058a · Cited by 316
Metadata
- Authors
- Nichols, J. M., Bishop, L. M., Bergman, R. G., & Ellman, J. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-08-23
- Volume
- 132
- Issue
- 36
- Pages
- 12554-12555
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2005960625
- Cited by
- 417
- References
- 3
- FWCI
- 11.65
- Type
- journal article
- Language
- en
- Open access
- green
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