The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
A Giant Surfactant of Polystyrene−(Carboxylic Acid-Functionalized Polyhedral Oligomeric Silsesquioxane) Amphiphile with Highly Stretched Polystyrene Tails in Micellar Assemblies
Abstract
A novel giant surfactant possessing a well-defined hydrophilic head and a hydrophobic polymeric tail, polystyrene-(carboxylic acid-functionalized polyhedral oligomeric silsesquioxane) conjugate (PS-APOSS), has been designed and synthesized via living anionic polymerization, hydrosilylation, and thiol-ene "click" chemistry. PS-APOSS forms micelles in selective solvents, and the micellar morphology can be tuned from vesicles to wormlike cylinders and further to spheres by increasing the degree of ionization of the carboxylic acid. The effect of APOSS-APOSS interactions was proven to be essential in the morphological transformation of the micelles. The PS tails in these micellar cores were found to be highly stretched in comparison with those in traditional amphiphilic block copolymers, and this can be explained in terms of minimization of free energy. This novel class of giant surfactants expands the scope of macromolecular amphiphiles and provides a platform for the study of the basic physical principles of their self-assembly behavior.
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Citations
Cites
Zhang, L., & Eisenberg, A. (1996) · Journal of the American Chemical Society · doi:10.1021/ja953709s · Cited by 1,262
On the origins of morphological complexity in block copolymer surfactants
Jain, S., & Bates, F. S. (2003) · Science · doi:10.1126/science.1082193 · Cited by 1,217
Cited by
Polymeric Surfactants: Synthesis, Properties, and Links to Applications
Raffa, P., Wever, D. A. Z., Picchioni, F., & Broekhuis, A. A. (2015) · Chemical Reviews · doi:10.1021/cr500129h · Cited by 389
Self-Assembly of Amphiphilic Plasmonic Micelle-Like Nanoparticles in Selective Solvents
He, J., Huang, X., Li, Y.-C., Liu, Y., Babu, T., Aronova, M. A., Wang, S., Lu, Z., Chen, X., & Nie, Z. (2013) · Journal of the American Chemical Society · doi:10.1021/ja402015s · Cited by 288
Newcomb, C. J., Moyer, T. J., Lee, S. S., & Stupp, S. I. (2012) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2012.09.004 · Cited by 76
Metadata
- Authors
- Yu, X., Zhong, S., Li, X., Tu, Y., Yang, S., Van Horn, R. M., Ni, C., Pochan, D. J., Quirk, R. P., Wesdemiotis, C., Zhang, W.-B., & Cheng, S. Z. D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-04
- Volume
- 132
- Issue
- 47
- Pages
- 16741-16744
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2334969099
- Cited by
- 251
- References
- 2
- FWCI
- 9.95
- Type
- journal article
- Language
- en
- Open access
- closed
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