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Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts
Open accessAbstract
Atom transfer radical addition of haloalkanes and α-halocarbonyls to olefins is efficiently performed with the photocatalyst Ir[(dF(CF(3))ppy)(2)(dtbbpy)]PF(6). This protocol is characterized by excellent yields, mild conditions, low catalyst loading, and broad scope. In addition, the atom transfer protocol can be used to quickly and efficiently introduce vinyl trifluoromethyl groups to olefins and access 1,1-cyclopropane diesters.
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Cited by
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Tang, X.-J., Thomoson, C. S., & Dolbier, W. R. (2014) · Organic Letters · doi:10.1021/ol502163f · Cited by 323
Metadata
- Authors
- Nguyen, J. D., Tucker, J. W., Konieczynska, M. D., & Stephenson, C. R. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-07
- Volume
- 133
- Issue
- 12
- Pages
- 4160-4163
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2093527245
- Cited by
- 772
- References
- 0
- FWCI
- 29.78
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts. https://app.cochat.ai/papers/10.1021/ja108560e
- The paper
- Nguyen, J. D., Tucker, J. W., Konieczynska, M. D., & Stephenson, C. R. J. (2011). Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts. Journal of the American Chemical Society. https://doi.org/10.1021/ja108560e
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
