The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Heteroepitaxial Growth of High-Index-Faceted Palladium Nanoshells and Their Catalytic Performance
Abstract
The development of high-performance nanocatalysts relies essentially on the generation of stable and active surface sites at the atomic scale through synthetic control of the size, shape, and chemical composition of nanoscale metals and metal oxides. One promising route is to induce the exposure of catalytically active high-index facets of nanostructures through shape-controlled syntheses. We have designed and prepared two types of Pd nanoshells that are enclosed by high-index {730} and {221} facets through heteroepitaxial growth on high-index-faceted Au nanocrystals. The turnover numbers per surface atom of the high-index-faceted Pd nanoshells have been found to be 3-7 times those of Pd and Au-Pd core-shell nanocubes that possess only {100} facets in catalyzing the Suzuki coupling reaction. These results open up a potential for the development of inexpensive and highly active metal nanocatalysts.
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Tian, N., Zhou, Z.-Y., Sun, S.-G., Ding, Y., & Wang, Z. L. (2007) · Science · doi:10.1126/science.1140484 · Cited by 3,073
The nature of the active site in heterogeneous metal catalysis
Nørskov, J. K., Bligaard, T., Hvolbæk, B., Abild-Pedersen, F., Chorkendorff, I., & Christensen, C. H. (2008) · Chemical Society Reviews · doi:10.1039/b800260f · Cited by 885
Mechanism of catalysis of hydrocarbon reactions by platinum surfaces
Somorjai, G. A., & Blakely, D. W. (1975) · Nature · doi:10.1038/258580a0 · Cited by 357
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Jiang, R., Li, B., Fang, C., & Wang, J. (2014) · Advanced Materials · doi:10.1002/adma.201400203 · Cited by 1,156
Self-citationHigh-Index Faceted Noble Metal Nanocrystals
Quan, Z., Wang, Y., & Fang, J. (2013) · Accounts of Chemical Research · doi:10.1021/ar200293n · Cited by 582
Synthesis and catalytic properties of bimetallic nanomaterials with various architectures
Liu, X., Wang, D., & Li, Y. (2012) · Nano Today · doi:10.1016/j.nantod.2012.08.003 · Cited by 538
Small Adsorbate‐Assisted Shape Control of Pd and Pt Nanocrystals
Chen, M., Wu, B., Yang, J., & Zheng, N. (2012) · Advanced Materials · doi:10.1002/adma.201104145 · Cited by 441
Nanointerface Chemistry: Lattice-Mismatch-Directed Synthesis and Application of Hybrid Nanocrystals
Liu, J., & Zhang, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00443 · Cited by 423
Metadata
- Authors
- Wang, F., Li, C., Sun, L.-D., Wu, H., Ming, T., Wang, J., Yu, J. C., & Yan, C.-H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-12-21
- Volume
- 133
- Issue
- 4
- Pages
- 1106-1111
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2313307537
- Cited by
- 296
- References
- 3
- FWCI
- 19.10
- Type
- journal article
- Language
- en
- Open access
- closed
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