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Catalytic Hydrogenation of Carboxamides and Esters by Well-Defined Cp*Ru Complexes Bearing a Protic Amine Ligand
Abstract
A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.
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Cited by
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Dub, P. A., & Ikariya, T. (2012) · ACS Catalysis · doi:10.1021/cs300341g · Cited by 386
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Metadata
- Authors
- Ito, M., Ootsuka, T., Watari, R., Shiibashi, A., Himizu, A., & Ikariya, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-07
- Volume
- 133
- Issue
- 12
- Pages
- 4240-4242
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2323900808
- Cited by
- 209
- References
- 0
- FWCI
- 15.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Catalytic Hydrogenation of Carboxamides and Esters by Well-Defined Cp*Ru Complexes Bearing a Protic Amine Ligand. https://app.cochat.ai/papers/10.1021/ja1117254
- The paper
- Ito, M., Ootsuka, T., Watari, R., Shiibashi, A., Himizu, A., & Ikariya, T. (2011). Catalytic Hydrogenation of Carboxamides and Esters by Well-Defined Cp*Ru Complexes Bearing a Protic Amine Ligand. Journal of the American Chemical Society. https://doi.org/10.1021/ja1117254
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
