The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Water Splitting on Composite Plasmonic-Metal/Semiconductor Photoelectrodes: Evidence for Selective Plasmon-Induced Formation of Charge Carriers near the Semiconductor Surface
Abstract
A critical factor limiting the rates of photocatalytic reactions, including water splitting, on oxide semiconductors is the high rate of charge-carrier recombination. In this contribution, we demonstrate that this issue can be alleviated significantly by combining a semiconductor photocatalyst with tailored plasmonic-metal nanostructures. Plasmonic nanostructures support the formation of resonant surface plasmons in response to a photon flux, localizing electromagnetic energy close to their surfaces. We present evidence that the interaction of localized electric fields with the neighboring semiconductor allows for the selective formation of electron/hole (e(-)/h(+)) pairs in the near-surface region of the semiconductor. The advantage of the formation of e(-)/h(+) pairs near the semiconductor surface is that these charge carriers are readily separated from each other and easily migrate to the surface, where they can perform photocatalytic transformations.
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Citations
Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Cited by
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy
Linic, S., Christopher, P., & Ingram, D. B. (2011) · Nature Materials · doi:10.1038/nmat3151 · Cited by 4,852
Self-citationZheng, Q., Chu, W., Zhao, C., Zhang, L., Guo, H., Wang, Y., Jiang, X., & Zhao, J. (2019) · WIREs Computational Molecular Science · doi:10.1002/wcms.1411 · Cited by 452
Self‐Assembled Au/CdSe Nanocrystal Clusters for Plasmon‐Mediated Photocatalytic Hydrogen Evolution
Shi, R., Cao, Y., Bao, Y., Zhao, Y., Waterhouse, G. I. N., Fang, Z., Wu, L., Tung, C., Yin, Y., & Zhang, T. (2017) · Advanced Materials · doi:10.1002/adma.201700803 · Cited by 382
Gomathi Devi, L., & Kavitha, R. (2016) · Applied Surface Science · doi:10.1016/j.apsusc.2015.11.016 · Cited by 359
Recent Advances in Heterogeneous Photocatalytic Decolorization of Synthetic Dyes
Muhd Julkapli, N., Bagheri, S., & Bee Abd Hamid, S. (2014) · The Scientific World Journal · doi:10.1155/2014/692307 · Cited by 280
Rather, R. A., Singh, S., & Pal, B. (2017) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2016.11.017 · Cited by 74
Metadata
- Authors
- Ingram, D. B., & Linic, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-22
- Volume
- 133
- Issue
- 14
- Pages
- 5202-5205
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2333708789
- Cited by
- 856
- References
- 2
- FWCI
- 28.77
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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