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Efficient Visible-Light Photocatalytic Water Splitting by Minute Amounts of Gold Supported on Nanoparticulate CeO2 Obtained by a Biopolymer Templating Method
Open accessAbstract
When irradiated with visible light (λ > 400 nm) 1 wt % gold-supported ceria nanoparticles generate oxygen from water (10.5 μmol·h(-1)) more efficiently than the standard WO(3) (1.7 μmol·h(-1)) even under UV irradiation (9.5 μmol·h(-1)). This remarkable photocatalytic activity arises from a novel preparation method to reduce the particle size of ceria (5 nm) by means of electrostatic binding of Ce(4+) to alginate gel, subsequent supercritical CO(2) drying, and calcination. The low loading of Au is crucial for the observed high catalytic activity.
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Citations
Cites
Supported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
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Metadata
- Authors
- Primo, A., Marino, T., Corma, A., Molinari, R., & García, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-04-20
- Volume
- 133
- Issue
- 18
- Pages
- 6930-6933
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2034054062
- Cited by
- 453
- References
- 1
- FWCI
- 17.60
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
