The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
A General Thermolabile Protecting Group Strategy for Organocatalytic Metal−Organic Frameworks
Abstract
We present a general strategy for incorporating organocatalytic moieties into metal-organic frameworks (MOFs). The organocatalytic units are protected by a thermolabile protecting group during MOF synthesis and then unveiled by a simple postsynthetic heating step. The strategy is exemplified using a thermolabile tert-butoxycarbonyl (Boc) protecting group for a proline moiety, the removal of which endows the resulting cubic zinc(II) IRMOF with catalytic activity for asymmetric aldol reactions. The bulky Boc groups also prevent framework interpenetration, producing open MOFs that can admit relatively large substrates.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks
Cohen, S. M. (2012) · Chemical Reviews · doi:10.1021/cr200179u · Cited by 2,336
Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts
Xu, H., Gao, J., & Jiang, D. (2015) · Nature Chemistry · doi:10.1038/nchem.2352 · Cited by 1,643
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials
Kirchon, A., Feng, L., Drake, H. F., Joseph, E. A., & Zhou, H.-C. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00688a · Cited by 1,448
Metal Organic Framework Catalysis: Quo vadis?
Gascon, J., Corma, A., Kapteijn, F., & Llabrés i Xamena, F. X. (2014) · ACS Catalysis · doi:10.1021/cs400959k · Cited by 960
Chiral Metal–Organic Frameworks
Gong, W., Chen, Z., Dong, J., Liu, Y., & Cui, Y. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00740 · Cited by 579
Bioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
Wang, K.-Y., Zhang, J., Hsu, Y.-C., Lin, H., Han, Z., Pang, J., Yang, Z., Liang, R.-R., Shi, W., & Zhou, H.-C. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00879 · Cited by 490
Tailored crystalline microporous materials by post-synthesis modification
Valtchev, V., Majano, G., Mintova, S., & Pérez-Ramírez, J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35196j · Cited by 478
Pore Chemistry of Metal–Organic Frameworks
Ji, Z., Wang, H., Canossa, S., Wuttke, S., & Yaghi, O. M. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000238 · Cited by 459
Photoactive Chiral Metal–Organic Frameworks for Light-Driven Asymmetric α-Alkylation of Aldehydes
Wu, P., He, C., Wang, J., Peng, X., Li, X., An, Y., & Duan, C. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305367j · Cited by 445
Joarder, B., Desai, A. V., Samanta, P., Mukherjee, S., & Ghosh, S. K. (2015) · Chemistry – A European Journal · doi:10.1002/chem.201405167 · Cited by 334
Activation of metal–organic framework materials
Mondloch, J. E., Karagiaridi, O., Farha, O. K., & Hupp, J. T. (2013) · CrystEngComm · doi:10.1039/c3ce41232f · Cited by 324
Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals
Dhakshinamoorthy, A., Opanasenko, M., Čejka, J., & Garcia, H. (2013) · Catalysis Science & Technology · doi:10.1039/c3cy00350g · Cited by 296
Qin, J.-S., Du, D.-Y., Li, W.-L., Zhang, J.-P., Li, S.-L., Su, Z.-M., Wang, X.-L., Xu, Q., Shao, K.-Z., & Lan, Y.-Q. (2012) · Chemical Science · doi:10.1039/c2sc00017b · Cited by 293
Taking organic reactions over metal-organic frameworks as heterogeneous catalysis
Hu, M.-L., Safarifard, V., Doustkhah, E., Rostamnia, S., Morsali, A., Nouruzi, N., Beheshti, S., & Akhbari, K. (2018) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2017.07.057 · Cited by 283
Engineering chiral porous metal-organic frameworks for enantioselective adsorption and separation
Peng, Y., Gong, T., Zhang, K., Lin, X., Liu, Y., Jiang, J., & Cui, Y. (2014) · Nature Communications · doi:10.1038/ncomms5406 · Cited by 275
Li, B., Leng, K., Zhang, Y., Dynes, J. J., Wang, J., Hu, Y., Ma, D., Shi, Z., Zhu, L., Zhang, D., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b01352 · Cited by 264
Metadata
- Authors
- Lun, D. J., Waterhouse, G. I. N., & Telfer, S. G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-28
- Volume
- 133
- Issue
- 15
- Pages
- 5806-5809
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2029164545
- Cited by
- 330
- References
- 1
- FWCI
- 24.31
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
