The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
High-Order Multiblock Copolymers via Iterative Cu(0)-Mediated Radical Polymerizations (SET-LRP): Toward Biological Precision
Abstract
We report a new approach for the facile synthesis of high-order multiblock copolymers comprising very short blocks. The approach entails sequential addition of different monomers via an iterative single electron transfer-living radical polymerization technique, allowing nearly perfect control of the copolymer microstructure. It is possible to synthesize high-order multiblock copolymers with unprecedented control, i.e., A-B-C-D-E-etc., without any need for purification between iterative 24 h block formation steps. To illustrate this concept, we report the synthesis of model P(MA-b-MA...) homopolymer and P(MA-b-nBuA-b-EA-b-2EHA-b-EA-b-nBuA) copolymer in extremely high yield. Finally, the halide end-group can be modified via "click chemistry", including thiol-bromide click chemistry, sodium methanethiosulfonate nucleophilic substitution, and atom transfer radical nitroxide coupling reaction, to yield functional, structurally complex macromolecules.
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Citations
Cites
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Cited by
Xu, J., Jung, K., Atme, A., Shanmugam, S., & Boyer, C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501745g · Cited by 990
Self-citationControlled/Living Radical Polymerization in Dispersed Systems: An Update
Zetterlund, P. B., Thickett, S. C., Perrier, S., Bourgeat-Lami, E., & Lansalot, M. (2015) · Chemical Reviews · doi:10.1021/cr500625k · Cited by 485
Self-citationMechanochemical bond scission for the activation of drugs
Huo, S., Zhao, P., Shi, Z., Zou, M., Yang, X., Warszawik, E., Loznik, M., Göstl, R., & Herrmann, A. (2021) · Nature Chemistry · doi:10.1038/s41557-020-00624-8 · Cited by 322
SARA ATRP or SET-LRP. End of controversy?
Konkolewicz, D., Wang, Y., Krys, P., Zhong, M., Isse, A. A., Gennaro, A., & Matyjaszewski, K. (2014) · Polymer Chemistry · doi:10.1039/c4py00149d · Cited by 314
Xu, J., Jung, K., & Boyer, C. (2014) · Macromolecules · doi:10.1021/ma500883y · Cited by 304
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Metadata
- Authors
- Soeriyadi, A. H., Boyer, C., Nyström, F., Zetterlund, P. B., & Whittaker, M. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-06-30
- Volume
- 133
- Issue
- 29
- Pages
- 11128-11131
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2316585167
- Cited by
- 326
- References
- 1
- FWCI
- 16.76
- Type
- journal article
- Language
- en
- Open access
- closed
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