The DOI matches its Crossref record; 80 of the 80 references it cites were found in a registry or an index.
Oxygen Tolerance Study of Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) Polymerization Mediated by Ru(bpy)3Cl2
Abstract
This study reports a highly efficient photoredox catalyst, Ru(bpy) 3 Cl 2, capable of controlling the polymerization of methacrylates, acrylates, and acrylamides in the presence of thiocarbonylthio compounds via a photoinduced electron transfer–reversible addition–fragmentation chain (PET-RAFT) process. This polymerization technique was performed in a closed vessel in the presence or absence of air. Online Fourier transform near-infrared spectroscopy (FTNIR) was employed to monitor the monomer conversions of methyl methacrylate, methyl acrylate, and N,N ′-dimethylacrylamide in the presence or absence of air. Interestingly, after an induction period, the polymerization proceeded in the presence of air to yield well-defined polymers (PDI < 1.20). The polymers were characterized by 1 H NMR, UV–vis spectroscopy, and gel permeation chromatography. Excellent end-group retention was also demonstrated by NMR, UV–vis, and successive chain extensions of the resulting homopolymers to yield diblock and multiblock copolymers (decablock copolymers).
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Cites
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Visible light photoredox catalysis: applications in organic synthesis
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New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
Hawker, C. J., Bosman, A. W., & Harth, E. (2001) · Chemical Reviews · doi:10.1021/cr990119u · Cited by 3,850
Metal-Catalyzed Living Radical Polymerization
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Visible light photocatalysis as a greener approach to photochemical synthesis
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Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives
Matyjaszewski, K. (2012) · Macromolecules · doi:10.1021/ma3001719 · Cited by 2,606
Visible‐Light Photoredox Catalysis
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Cited by
Metal-Free Atom Transfer Radical Polymerization
Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., Read de Alaniz, J., Fors, B. P., & Hawker, C. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja510389m · Cited by 939
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Yeow, J., Xu, J., & Boyer, C. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00523 · Cited by 266
Self-citationMachine Learning on a Robotic Platform for the Design of Polymer–Protein Hybrids
Tamasi, M. J., Patel, R. A., Borca, C. H., Kosuri, S., Mugnier, H., Upadhya, R., Murthy, N. S., Webb, M. A., & Gormley, A. J. (2022) · Advanced Materials · doi:10.1002/adma.202201809 · Cited by 177
Metadata
- Authors
- Xu, J., Jung, K., & Boyer, C.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-20
- Volume
- 47
- Issue
- 13
- Pages
- 4217-4229
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2313595743
- Cited by
- 304
- References
- 80
- FWCI
- 14.74
- Type
- journal article
- Language
- en
- Open access
- closed
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