The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Electrocatalytic Water Oxidation Beginning with the Cobalt Polyoxometalate [Co4(H2O)2(PW9O34)2]10–: Identification of Heterogeneous CoOx as the Dominant Catalyst
Abstract
The question of "what is the true catalyst?" when beginning with the cobalt polyoxometalate (POM) [Co(4)(H(2)O)(2)(PW(9)O(34))(2)](10-) in electrochemical water oxidation catalysis is examined in pH 8.0 sodium phosphate buffer at a glassy carbon electrode. Is [Co(4)(H(2)O)(2)(PW(9)O(34))(2)](10-) a true water oxidation catalyst (WOC), or just a precatalyst? Electrochemical, kinetic, UV-vis, SEM, EDX, and other data provide four main lines of compelling evidence that, under the conditions used herein, the dominant WOC is actually heterogeneous CoO(x) and not homogeneous [Co(4)(H(2)O)(2)(PW(9)O(34))(2)](10-).
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Cites
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Cited by
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
Leung, C.-F., Ng, S.-M., Ko, C.-C., Man, W.-L., Wu, J., Chen, L., & Lau, T.-C. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21840b · Cited by 206
Metadata
- Authors
- Stracke, J. J., & Finke, R. G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-09-06
- Volume
- 133
- Issue
- 38
- Pages
- 14872-14875
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1988013267
- Cited by
- 424
- References
- 1
- FWCI
- 21.84
- Type
- journal article
- Language
- en
- Open access
- closed
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