A cobalt(ii) quaterpyridine complex as a visible light-driven catalyst for both water oxidation and reduction
Abstract
The complex [CoII(qpy)(OH2)2]2+ (qpy = 2,2′:6′,2′′:6′′,2′′′-quaterpyridine) is an efficient visible light-driven catalyst for both water oxidation and reduction. It catalyses photochemical oxygen evolution from water at pH 8.0 with [RuII(bpy)3]2+/S2O82− (λ = 457 nm, max TON = 335, bpy = 2,2′-bipyridine). It also catalyses photochemical hydrogen generation from [IrIII(dF(CF3)ppy)2(dtbbpy)]+/TEOA (dF(CF3)ppy = anion of 2-(2,4-difluorophenyl)-5-trifluoromethylpyridine, dtbbpy = 4,4′-di-tert-butyl-2,2′-bipyridine, TEOA = triethanolamine) in aqueous acetonitrile (λ > 420 nm, max TON = 1730).
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Great progress has been made in adopting molecular metal complexes to mimic the basic principles of photosynthesis for H2 generation.
“Moreover, great progress has been made in adopting molecular metal complexes to mimic the basic principles of photosynthesis for H 2 generation.”
From 2D Transition‐Metal‐Dichalcogenide‐Nanosheet‐Based Composites for Photocatalytic and Electrocatalytic Hydrogen Evolution Reactions (2016) · cites this paper as [183]
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- Authors
- Leung, C.-F., Ng, S.-M., Ko, C.-C., Man, W.-L., Wu, J., Chen, L., & Lau, T.-C.
- Affiliations
- City University of Hong Kong (HK)
- Corresponding author
- Lau, Tai-Chu
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 7
- Pages
- 7903
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W1986412806
- Cited by
- 206
- References
- 44
- Citations by year
- 2026: 5 · 2025: 6 · 2024: 7 · 2023: 6 · 2022: 11 · 2021: 13 · 2020: 12 · 2019: 15 · 2018: 17 · 2017: 14 · 2016: 29 · 2015: 27 · 2014: 25 · 2013: 13 · 2012: 6
- FWCI
- 8.72
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Energy & Environmental Science (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Catalyzed Oxygenation Mechanisms
- Keywords
- visible light photocatalysis, water oxidation, water reduction, photochemical hydrogen evolution, oxygen evolution reaction, acetonitrile
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