The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
The Particle Size Effect on the Oxygen Reduction Reaction Activity of Pt Catalysts: Influence of Electrolyte and Relation to Single Crystal Models
Abstract
The influence of particle size on the oxygen reduction reaction (ORR) activity of Pt was examined in three different electrolytes: two acidic solutions, with varying anionic adsorption strength (HClO(4) < H(2)SO(4)); and an alkaline solution (KOH). The experiments show that the absolute ORR rate is dependent on the supporting electrolyte; however, the relationship between activity and particle size is rather independent of the supporting electrolyte. The specific activity (SA) toward the ORR rapidly decreases in the order of polycrystalline Pt > unsupported Pt black particles (~30 nm) > high surface area (HSA) carbon supported Pt nanoparticle catalysts (of various size between 1 and 5 nm). In contrast to previous work, it is highlighted that the difference in SA between the individual HSA carbon supported catalysts (1 to 5 nm) is rather trivial and that the main challenge is to understand the significant differences in SA between the polycrystalline Pt, unsupported Pt particles, and HSA carbon supported Pt catalysts. Finally, a comparison between measured and modeled activities (based on the distribution of surface planes and their SAs) for different particle sizes indicates that such simple models do not capture all aspects of the behavior of HSA carbon supported catalysts.
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Cites
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Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
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Self-citationIdentification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
Herzing, A. A., Kiely, C. J., Carley, A. F., Landon, P., & Hutchings, G. J. (2008) · Science · doi:10.1126/science.1159639 · Cited by 1,530
Characterization of High‐Surface‐Area Electrocatalysts Using a Rotating Disk Electrode Configuration
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Particle Size Effects for Oxygen Reduction on Highly Dispersed Platinum in Acid Electrolytes
Kinoshita, K. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086566 · Cited by 854
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Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Design criteria for stable Pt/C fuel cell catalysts
Meier, J. C., Galeano, C., Katsounaros, I., Witte, J., Bongard, H. J., Topalov, A. A., Baldizzone, C., Mezzavilla, S., Schüth, F., & Mayrhofer, K. J. J. (2014) · Beilstein Journal of Nanotechnology · doi:10.3762/bjnano.5.5 · Cited by 559
Self-citationOezaslan, M., Hasché, F., & Strasser, P. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.106204jes · Cited by 239
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Metadata
- Authors
- Nesselberger, M., Ashton, S., Meier, J. C., Katsounaros, I., Mayrhofer, K. J. J., & Arenz, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-10-11
- Volume
- 133
- Issue
- 43
- Pages
- 17428-17433
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2065414271
- Cited by
- 528
- References
- 7
- FWCI
- 16.02
- Type
- journal article
- Language
- en
- Open access
- closed
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