Electronic metal-support interaction enhanced oxygen reduction activity and stability of boron carbide supported platinum
Open accessAbstract
Catalysing the reduction of oxygen in acidic media is a standing challenge. Although activity of platinum, the most active metal, can be substantially improved by alloying, alloy stability remains a concern. Here we report that platinum nanoparticles supported on graphite-rich boron carbide show a 50–100% increase in activity in acidic media and improved cycle stability compared to commercial carbon supported platinum nanoparticles. Transmission electron microscopy and x-ray absorption fine structure analysis confirm similar platinum nanoparticle shapes, sizes, lattice parameters, and cluster packing on both supports, while x-ray photoelectron and absorption spectroscopy demonstrate a change in electronic structure. This shows that purely electronic metal-support interactions can significantly improve oxygen reduction activity without inducing shape, alloying or strain effects and without compromising stability. Optimizing the electronic interaction between the catalyst and support is, therefore, a promising approach for advanced electrocatalysts where optimizing the catalytic nanoparticles themselves is constrained by other concerns.
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A tiny peak shift in the Pt 4f core-level XPS spectrum is evidence of the electronic modification of the Pt 5d band by either charge transfer or alloy formation with the support.
“A tiny peak shift in the Pt 4f core-level XPS spectrum is evidence of the electronic modification of the Pt 5d band by either charge transfer or alloy formation with the support.72,76,77”
From Highly Dispersed Pt Clusters on F-Doped Tin(IV) Oxide Aerogel Matrix: An Ultra-Robust Hybrid Catalyst for Enhanced Hydrogen Evolution (2022) · cites this paper as [72]
The Results sections on X-ray photoelectron spectroscopy and electronic metal-support interaction report a ~0.6 eV Pt 4f shift and interpret it as evidence of changed electronic occupancy associated with charge transfer. The paper initially considers alloy formation as an alternative, but reports no evidence for it and assigns the observed shift to purely electronic effects. It discusses Pt d-band occupancy separately using XANES, so the XPS shift alone does not establish the full claim. (LLM, conf=0.86)
Experimental — accuracy not yet measuredElectronic metal support interaction (EMSI) through the charge transfer phenomenon comes into effect.
“electronic metal support interaction (EMSI) through the charge transfer phenomenon comes into effect.71,72”
From Highly Dispersed Pt Clusters on F-Doped Tin(IV) Oxide Aerogel Matrix: An Ultra-Robust Hybrid Catalyst for Enhanced Hydrogen Evolution (2022) · cites this paper as [72]
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Cites
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
Ravel, B., & Newville, M. G. (2005) · Journal of Synchrotron Radiation · doi:10.1107/s0909049505012719 · Cited by 16,981 · see citing works
Gasteiger, H. A., Kocha, S. S., Sompalli, B., & Wagner, F. T. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2004.06.021 · Cited by 4,876 · see citing works
Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421 · see citing works
Towards the computational design of solid catalysts
Nørskov, J. K., Bligaard, T., Rossmeisl, J., & Christensen, C. H. (2009) · Nature Chemistry · doi:10.1038/nchem.121 · Cited by 4,161 · see citing works
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
Greeley, J., Stephens, I. E. L., Bondarenko, A. S., Johansson, T. P., Hansen, H. A., Jaramillo, T. F., Rossmeisl, J., Chorkendorff, I., & Nørskov, J. K. (2009) · Nature Chemistry · doi:10.1038/nchem.367 · Cited by 3,203 · see citing works
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts
Strasser, P., Koh, S., Anniyev, T., Greeley, J., More, K., Yu, C., Liu, Z., Kaya, S., Nordlund, D., Ogasawara, H., et al. (2010) · Nature Chemistry · doi:10.1038/nchem.623 · Cited by 2,984 · see citing works
Stamenkovic, V., Mun, B. S., Mayrhofer, K. J. J., Ross, P. N., Markovic, N. M., Rossmeisl, J., Greeley, J., & Nørskov, J. K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200504386 · Cited by 2,109 · see citing works
A review of PEM fuel cell durability: Degradation mechanisms and mitigation strategies
Wu, J., Yuan, X. Z., Martin, J. J., Wang, H., Zhang, J., Shen, J., Wu, S., & Merida, W. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.06.006 · Cited by 1,587 · see citing works
Paulus, U. A., Schmidt, T. J., Gasteiger, H. A., & Behm, R. J. (2001) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(00)00407-1 · Cited by 1,428 · see citing works
Mukerjee, S., Srinivasan, S., Soriaga, M. P., & McBreen, J. (1995) · Journal of The Electrochemical Society · doi:10.1149/1.2048590 · Cited by 1,155 · see citing works
Oxygen Reduction Reaction on Pt and Pt Bimetallic Surfaces: A Selective Review
Marković, N. M., Schmidt, T. J., Stamenković, V. R., & Ross, P. N. (2001) · Fuel Cells · doi:10.1002/1615-6854(200107)1:2 · Cited by 1,135 · see citing works
Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC
Yu, X., & Ye, S. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2007.07.048 · Cited by 1,098 · see citing works
Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction
Escudero-Escribano, M., Malacrida, P., Hansen, M. H., Vej-Hansen, U. G., Velázquez-Palenzuela, A., Tripkovic, V., Schiøtz, J., Rossmeisl, J., Stephens, I. E. L., & Chorkendorff, I. (2016) · Science · doi:10.1126/science.aad8892 · Cited by 1,057 · see citing works
Mayrhofer, K. J. J., Strmcnik, D. S., Blizanac, B. B., Stamenković, V. R., Arenz, M., & Marković, N. M. (2007) · Electrochimica Acta · doi:10.1016/j.electacta.2007.11.057 · Cited by 980 · see citing works
A Reverse-Current Decay Mechanism for Fuel Cells
Reiser, C., Bregoli, L. J., Patterson, T. W., Yi, J. S., Yang, J., Perry, M. L., & Jarvi, T. D. (2005) · Electrochemical and Solid-State Letters · doi:10.1149/1.1896466 · Cited by 977 · see citing works
Particle Size Effects for Oxygen Reduction on Highly Dispersed Platinum in Acid Electrolytes
Kinoshita, K. (1990) · Journal of The Electrochemical Society · doi:10.1149/1.2086566 · Cited by 854 · see citing works
Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges
Rabis, A., Rodríguez, P., & Schmidt, T. J. (2012) · ACS Catalysis · doi:10.1021/cs3000864 · Cited by 781 · see citing works
Markovic, N. M., Gasteiger, H. A., & Ross, P. N. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100011a001 · Cited by 736 · see citing works
Garsany, Y., Baturina, O. A., Swider‐Lyons, K. E., & Kocha, S. S. (2010) · Analytical Chemistry · doi:10.1021/ac100306c · Cited by 704 · see citing works
Direct evaluation of the sp3 content in diamond-like-carbon films by XPS
Mérel, P., Tabbal, M., Chaker, M., Moisa, S., & Margot, J. (1998) · Applied Surface Science · doi:10.1016/s0169-4332(98)00319-5 · Cited by 694 · see citing works
A View from the Inside: Complexity in the Atomic Scale Ordering of Supported Metal Nanoparticles
Frenkel, A. I., Hills, C. W., & Nuzzo, R. G. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp012769j · Cited by 649 · see citing works
Zhou, Y., Neyerlin, K. C., Olson, T. S., Pylypenko, S., Bult, J. B., Dinh, H. N., Gennett, T., Shao, Z., & O’Hayre, R. (2010) · Energy & Environmental Science · doi:10.1039/c003710a · Cited by 644 · see citing works
Wakisaka, M., Mitsui, S., Hirose, Y., Kawashima, K., Uchida, H., & Watanabe, M. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0653510 · Cited by 534 · see citing works
Nesselberger, M., Ashton, S., Meier, J. C., Katsounaros, I., Mayrhofer, K. J. J., & Arenz, M. (2011) · Journal of the American Chemical Society · doi:10.1021/ja207016u · Cited by 525 · see citing works
Metal Carbides as Alternative Electrocatalyst Supports
Liu, Y., Kelly, T. G., Chen, J. G., & Mustain, W. E. (2013) · ACS Catalysis · doi:10.1021/cs4001249 · Cited by 485 · see citing works
Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC
Yu, X., & Ye, S. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2007.07.049 · Cited by 480 · see citing works
Maillard, F., Schreier, S., Hanzlik, M., Savinova, E. R., Weinkauf, S., & Stimming, U. (2005) · Phys. Chem. Chem. Phys. · doi:10.1039/b411377b · Cited by 448 · see citing works
Advanced Platinum Alloy Electrocatalysts for the Oxygen Reduction Reaction
Wang, C., Markovic, N. M., & Stamenkovic, V. R. (2012) · ACS Catalysis · doi:10.1021/cs3000792 · Cited by 440 · see citing works
Determination of Catalyst Unique Parameters for the Oxygen Reduction Reaction in a PEMFC
Neyerlin, K. C., Gu, W., Jorné, J., & Gasteiger, H. A. (2006) · Journal of The Electrochemical Society · doi:10.1149/1.2266294 · Cited by 428 · see citing works
Green, C. L., & Kucernak, A. R. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0131931 · Cited by 423 · see citing works
Cheon, J. Y., Kim, J. H., Kim, J. H., Goddeti, K. C., Park, J. Y., & Joo, S. H. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503557x · Cited by 411 · see citing works
Mansour, A. N., Cook, J. W., & Sayers, D. E. (1984) · The Journal of Physical Chemistry · doi:10.1021/j150655a029 · Cited by 394 · see citing works
The effect of particle proximity on the oxygen reduction rate of size-selected platinum clusters
Nesselberger, M., Röefzaad, M., Hamou, R. F., Biedermann, P. U., Schweinberger, F. F., Kunz, S., Schlögl, K., Wiberg, G. K. H., Ashton, S., Heiz, U., et al. (2013) · Nature Materials · doi:10.1038/nmat3712 · Cited by 387 · see citing works
Estimation of mean size and shape of small metal particles by EXAFS
Jentys, A. (1999) · Physical Chemistry Chemical Physics · doi:10.1039/a904654b · Cited by 383 · see citing works
Dulub, O., Hebenstreit, W., & Diebold, U. (2000) · Physical Review Letters · doi:10.1103/physrevlett.84.3646 · Cited by 367 · see citing works
Lewera, A., Timperman, L., Roguska, A., & Alonso‐Vante, N. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp2068446 · Cited by 362 · see citing works
Chen, S., Gasteiger, H. A., Hayakawa, K., Tada, T., & Shao-Horn, Y. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3258275 · Cited by 360 · see citing works
Development of Supported Bifunctional Electrocatalysts for Unitized Regenerative Fuel Cells
Chen, G., Bare, S. R., & Mallouk, T. E. (2002) · Journal of The Electrochemical Society · doi:10.1149/1.1491237 · Cited by 322 · see citing works
Blizanac, B. B., ROSS, P. N. J., & Marković, N. M. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp056050d · Cited by 317 · see citing works
Ceramic materials as supports for low-temperature fuel cell catalysts
Antolini, E., & Gonzalez, E. R. (2009) · Solid State Ionics · doi:10.1016/j.ssi.2009.03.007 · Cited by 284 · see citing works
Impact of film drying procedures on RDE characterization of Pt/VC electrocatalysts
Garsany, Y., Singer, I. L., & Swider‐Lyons, K. E. (2011) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2011.09.016 · Cited by 223 · see citing works
Don't Forget Long-Term Fundamental Research in Energy
Whitesides, G. M., & Crabtree, G. W. (2007) · Science · doi:10.1126/science.1140362 · Cited by 213 · see citing works
Degradation of Carbon-Supported Pt Bimetallic Nanoparticles by Surface Segregation
Mayrhofer, K. J. J., Hartl, K., Juhart, V., & Arenz, M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9074216 · Cited by 202 · see citing works
Direct XPS Evidence for Charge Transfer from a Reduced Rutile TiO2(110) Surface to Au Clusters
Jiang, Z., Zhang, W., Li, J., Yang, X. W., Xu, F., Zhu, J., & Huang, W. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp073446b · Cited by 189 · see citing works
Xiong, L., & Manthiram, A. (2004) · Electrochimica Acta · doi:10.1016/j.electacta.2004.04.011 · Cited by 178 · see citing works
Huang, S.-Y., Ganesan, P., & Popov, B. N. (2010) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2010.11.026 · Cited by 173 · see citing works
Behavior of Disordered Boron Carbide under Stress
Fanchini, G., McCauley, J. W., & Chhowalla, M. (2006) · Physical Review Letters · doi:10.1103/physrevlett.97.035502 · Cited by 159 · see citing works
Du, M., Cui, L., Cao, Y. H., & Bard, A. J. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b03034 · Cited by 153 · see citing works
Takasaki, F., Matsuie, S., Takabatake, Y., Noda, Z., Hayashi, A., Shiratori, Y., Ito, K., & Sasaki, K. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3625918 · Cited by 144 · see citing works
The Effect of Platinum Loading and Surface Morphology on Oxygen Reduction Activity
Taylor, S. M., Fabbri, E., Levecque, P. B. J., Schmidt, T. J., & Conrad, O. (2016) · Electrocatalysis · doi:10.1007/s12678-016-0304-3 · Cited by 131 · see citing works
Self-citationThermionic emission and work function of multiwalled carbon nanotube yarns
Liu, P., Wei, Y., Jiang, K., Sun, Q., Zhang, X., Fan, S., Zhang, S., Ning, C., & Deng, J. (2006) · Physical Review B · doi:10.1103/physrevb.73.235412 · Cited by 112 · see citing works
High Sensitivity Silicon Slit Detectors for 1 nm Powder XRD Size Detection Limit
O’Connell, K. M., & Regalbuto, J. R. (2015) · Catalysis Letters · doi:10.1007/s10562-015-1479-6 · Cited by 96 · see citing works
Ma, J., Habrioux, A., Morais, C. M., Lewera, A., Vogel, W., Verde‐Gómez, Y., Ramos‐Sánchez, G., Balbuena, P. B., & Alonso‐Vante, N. (2013) · ACS Catalysis · doi:10.1021/cs4003222 · Cited by 90 · see citing works
Work Function of Metals and the Potential at Which They Have Zero Charge in Contact with Solutions
Bockris, J. O., & Argade, S. D. (1968) · The Journal of Chemical Physics · doi:10.1063/1.1670009 · Cited by 87 · see citing works
Geometrical Characteristics of Regular Polyhedra: Application to EXAFS Studies of Nanoclusters
Glasner, D., & Frenkel, A. I. (2007) · AIP conference proceedings · doi:10.1063/1.2644651 · Cited by 78 · see citing works
Metal-support interactions in heterogeneous catalysis
Joyner, R. W., Pendry, J. B., Saldin, D. K., & Tennison, S. R. (1984) · Surface Science · doi:10.1016/0039-6028(84)90497-7 · Cited by 76 · see citing works
The Effect of Platinum Nanoparticle Distribution on Oxygen Electroreduction Activity and Selectivity
Fabbri, E., Taylor, S. M., Rabis, A., Levecque, P. B. J., Conrad, O., Kötz, R., & Schmidt, T. J. (2014) · ChemCatChem · doi:10.1002/cctc.201300987 · Cited by 70 · see citing works
Self-citationLv, H., Peng, T., Wu, P., Pan, M., & Mu, S. C. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm30538k · Cited by 68 · see citing works
Fabbri, E., Taylor, S. M., Rabis, A., Levecque, P. B. J., Conrad, O., Kötz, R., & Schmidt, T. J. (2014) · ChemCatChem · doi:10.1002/cctc.201490028 · Cited by 47 · see citing works
Self-citationMetal Oxide‐Supported Platinum Overlayers as Proton‐Exchange Membrane Fuel Cell Cathodes
Tripković, V., Abild‐Pedersen, F., Studt, F., Cerri, I., Nagami, T., Bligaard, T., & Rossmeisl, J. (2012) · ChemCatChem · doi:10.1002/cctc.201100308 · Cited by 46 · see citing works
Assumpção, M. H. M. T., Moraes, A., Souza, R. F. B. D., Reis, R. M., Rocha, R. S., Gaubeur, I., Calegaro, M. L., Hammer, P., Lanza, M. R. V., & Santos, M. C. (2013) · Applied Catalysis A General · doi:10.1016/j.apcata.2013.04.008 · Cited by 43 · see citing works
Boron Carbide, a New Substrate for Fuel Cell Electrocatalysts
Grubb, W. T., & McKee, D. W. (1966) · Nature · doi:10.1038/210192b0 · Cited by 41 · see citing works
The dependence of the work function of carbon black on surface acidity
Fabish, T. J., & Hair, M. L. (1977) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(77)90060-1 · Cited by 38 · see citing works
Rabis, A., Kramer, D., Fabbri, E., Worsdale, M., Kötz, R., & Schmidt, T. J. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp4120139 · Cited by 36 · see citing works
Self-citationElectronic charge transfer between Au nano-particles and TiO2-terminated SrTiO3(001) substrate
Mitsuhara, K., Kitsudo, Y., Matsumoto, H., Visikovskiy, A., Takizawa, M., Nishimura, T., Akita, T., & Kido, Y. (2009) · Surface Science · doi:10.1016/j.susc.2009.12.024 · Cited by 33 · see citing works
Yoshitake, H., Mochizuki, T., Yamazaki, O., & Ota, K. (1993) · Journal of Electroanalytical Chemistry · doi:10.1016/0022-0728(93)87059-5 · Cited by 30 · see citing works
Naidoo, Q., Naidoo, S., Petrik, L. F., Nechaev, A. N., & Ndungu, P. G. (2012) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2012.03.050 · Cited by 29 · see citing works
Synthesis of boron carbide nanoflakes via a bamboo-based carbon thermal reduction method
Du, J., Li, Q., Xia, Y., Cheng, X., Gan, Y., Huang, H., Zhang, W., & Tao, X. (2013) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2013.07.051 · Cited by 29 · see citing works
Ding, H., & Hihara, L. H. (2011) · Journal of The Electrochemical Society · doi:10.1149/1.3567519 · Cited by 29 · see citing works
Characterization by XPS and SEM of reactive chemical vapour deposited boron carbide on carbon fibre
Vincent, C., Vincent, H., Mourichoux, H., & Bouix, J. (1992) · Journal of Materials Science · doi:10.1007/bf01107217 · Cited by 24 · see citing works
Flagged first, then by citations
Research works printed but not linked: 2
- Stamenkovic V.. Improved oxygen reduction activity on Pt3Ni(111) via increased surface site availability. Science 315, 493– 497 (2007). 17218494
- Mukerjee S., Srinivasan S. & Soriaga M. P. Role of structural and electronic properties of Pt and Pt alloys on electrocatalysis of oxygen reduction. J. Electrochem. Soc. 142, 1409 (1995).
Cited by
Sorted by citations
Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity
van Deelen, T. W., Mejía, C. H., & de Jong, K. P. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0364-x · Cited by 2,379 · see citing works
Zhao, Y., Saseendran, D. P. A., Huang, C., Triana, C. A., Marks, W. R., Chen, H., Zhao, H., & Patzke, G. R. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00515 · Cited by 822 · see citing works
Jiang, R., Li, L., Sheng, T., Hu, G., Chen, Y., & Wang, L. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b07294 · Cited by 797 · see citing works
Li, J., Guan, Q., Wu, H. P., Liu, W., Lin, Y., Sun, Z., Ye, X., Zheng, X., Pan, H., Zhu, J., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b06482 · Cited by 747 · see citing works
A Theory/Experience Description of Support Effects in Carbon-Supported Catalysts
Gerber, I. C., & Serp, P. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00209 · Cited by 742 · see citing works
Descriptors for the Evaluation of Electrocatalytic Reactions: d‐Band Theory and Beyond
Jiao, S., Fu, X., & Huang, H. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202107651 · Cited by 727 · see citing works
Yan, Q., Wu, D., Chu, S.-Q., Chen, Z.-Q., Lin, Y., Chen, M., Zhang, J., Wu, X., & Liang, H. (2019) · Nature Communications · doi:10.1038/s41467-019-12851-w · Cited by 448 · see citing works
Electrocatalytic Hydrogenation of Biomass-Derived Organics: A Review
Akhade, S. A., Singh, N., Gutiérrez, O. Y., Lopez‐Ruiz, J. A., Wang, H., Holladay, J. D., Liu, Y., Karkamkar, A., Weber, R. S., Padmaperuma, A. B., et al. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00158 · Cited by 447 · see citing works
Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis
Leybo, D. V., Etim, U. J., Monai, M., Bare, S. R., Zhong, Z., & Vogt, C. (2024) · Chemical Society Reviews · doi:10.1039/d4cs00527a · Cited by 432 · see citing works
The Critical Impacts of Ligands on Heterogeneous Nanocatalysis: A Review
Lu, L., Zou, S., & Fang, B. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c00903 · Cited by 357 · see citing works
Liu, D., He, Q., Ding, S., & Song, L. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001482 · Cited by 308 · see citing works
Alarawi, A., Ramalingam, V., & He, J. (2018) · Materials Today Energy · doi:10.1016/j.mtener.2018.10.014 · Cited by 229 · see citing works
Wu, X., Feng, B., Li, W., Niu, Y., Yu, Y., Lu, S., Zhong, C., Liu, P., Tian, Z., Chen, L., et al. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.05.034 · Cited by 205 · see citing works
Metal-support interaction for heterogeneous catalysis: from nanoparticles to single atoms
Lou, Y., Xu, J., Zhang, Y., Pan, C., Dong, Y., & Zhu, Y. (2020) · Materials Today Nano · doi:10.1016/j.mtnano.2020.100093 · Cited by 201 · see citing works
Li, L., Wang, B., Zhang, G., Yang, G., Yang, T., Yang, S. X., & Yang, S. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001600 · Cited by 187 · see citing works
Zhang, S. M., Xia, Z., Ni, T., Zhang, Z., Ma, Y., & Qu, Y. (2018) · Journal of Catalysis · doi:10.1016/j.jcat.2018.01.004 · Cited by 185 · see citing works
Li, C., Kim, S. H., Lim, H. Y., Sun, Q., Jiang, Y., Noh, H., Kim, S., Baek, J., Kwak, S. K., & Baek, J. (2023) · Advanced Materials · doi:10.1002/adma.202301369 · Cited by 178 · see citing works
Diversity of platinum-sites at platinum/fullerene interface accelerates alkaline hydrogen evolution
Chen, J., Aliasgar, M., Buendía, F., Zhang, T., Zhao, Y., Lian, X., Wen, L., Yang, H., Sun, W., Kozlov, S. M., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-37404-0 · Cited by 174 · see citing works
Noble Metal‐Based Multimetallic Nanoparticles for Electrocatalytic Applications
Kim, H., Yoo, T. Y., Bootharaju, M. S., Kim, J. H., Chung, D. Y., & Hyeon, T. (2021) · Advanced Science · doi:10.1002/advs.202104054 · Cited by 168 · see citing works
Tian, S., Gong, W., Chen, W., Lin, N., Zhu, Y., Feng, Q., Xu, Q. S., Fu, Q., Chen, C., Luo, J., et al. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00322 · Cited by 125 · see citing works
Yu, J., Chen, W., He, F., Song, W., & Cao, C. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.2c10976 · Cited by 124 · see citing works
Sikdar, N., Junqueira, J. R. C., Dieckhöfer, S., Quast, T., Braun, M., Song, Y., Aiyappa, H. B., Seisel, S., Weidner, J., Öhl, D., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202108313 · Cited by 120 · see citing works
Wu, J., Liu, B., Fan, X., Ding, J., Han, X., Deng, Y., Hu, W., & Zhong, C. M. (2020) · Carbon Energy · doi:10.1002/cey2.60 · Cited by 119 · see citing works
Zhang, W., Chang, J., Wang, G., Li, Z., Wang, M., Zhu, Y., Li, B., Zhou, H., Wang, G., Gu, M. D., et al. (2022) · Energy & Environmental Science · doi:10.1039/d1ee03972e · Cited by 114 · see citing works
Carbon‐Based Substrates for Highly Dispersed Nanoparticle and Even Single‐Atom Electrocatalysts
Chen, Y., Zhang, X., & Zhou, Z. P. (2019) · Small Methods · doi:10.1002/smtd.201900050 · Cited by 112 · see citing works
Jayabal, S., Saranya, G., Geng, D., Lin, L., & Meng, X. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta01530j · Cited by 104 · see citing works
Fouzaï, I., Gentil, S., Bassetto, V. C., Silva, W. O., Maher, R., & Girault, H. H. (2021) · Journal of Materials Chemistry A · doi:10.1039/d0ta07470e · Cited by 102 · see citing works
Cheng, H., Cao, Z., Chen, Z., Zhao, M., Xie, M., Lyu, Z., Zhu, Z., Chi, M., & Younan Xia, A. (2019) · Nano Letters · doi:10.1021/acs.nanolett.9b01221 · Cited by 101 · see citing works
Wang, H., Gao, Z., Sun, B., Mu, S., Dang, F., Guo, X., Ma, D., & Shi, C. (2023) · Chem Catalysis · doi:10.1016/j.checat.2023.100768 · Cited by 100 · see citing works
Kim, T., Roy, S. B., Moon, S., Yoo, S., Choi, H., Parale, V. G., Kim, Y., Lee, J., Jun, S. C., Kang, K., et al. (2022) · ACS Nano · doi:10.1021/acsnano.1c10504 · Cited by 99 · see citing works
Supported Iridium‐based Oxygen Evolution Reaction Electrocatalysts ‐ Recent Developments
Moriau, L. J., Smiljanić, M., Lončar, A., & Hodnik, N. (2022) · ChemCatChem · doi:10.1002/cctc.202200586 · Cited by 96 · see citing works
Graphene based catalyst supports for high temperature PEM fuel cell application
Devrim, Y. G., Arıca, E. D., & Albostan, A. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.03.047 · Cited by 95 · see citing works
On the interpretation of X-ray photoelectron spectra of Pt-Cu bimetallic alloys
Khalakhan, I., Vorokhta, M., Xie, X., Piliai, L., & Matolı́nová, I. (2020) · Journal of Electron Spectroscopy and Related Phenomena · doi:10.1016/j.elspec.2020.147027 · Cited by 93 · see citing works
Yu, J., Su, C., Shang, L., & Zhang, T. (2023) · ACS Nano · doi:10.1021/acsnano.3c06522 · Cited by 93 · see citing works
Koh, K., Sanyal, U., Lee, M., Cheng, G., Song, M., Glezakou, V., Liu, Y., Li, D., Rousseau, R. J., Gutiérrez, O. Y., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201912241 · Cited by 87 · see citing works
Porous FeCo Glassy Alloy as Bifunctional Support for High‐Performance Zn‐Air Battery
Pan, F., Li, Z., Yang, Z., Ma, Q., Wang, M., Wang, H., Olszta, M. J., Wang, G., Feng, Z., Du, Y., et al. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202002204 · Cited by 86 · see citing works
Naik, K. M., Higuchi, E., & Inoue, H. (2020) · Journal of Power Sources · doi:10.1016/j.jpowsour.2020.227972 · Cited by 84 · see citing works
Naik, K. M., Higuchi, E., & Inoue, H. (2020) · Nanoscale · doi:10.1039/d0nr02092c · Cited by 84 · see citing works
Deng, X., Alfonso, D. R., Nguyen‐Phan, T., & Kauffman, D. R. (2023) · ACS Catalysis · doi:10.1021/acscatal.3c03446 · Cited by 82 · see citing works
Truong, H. B., Huy, B. T., Ray, S. K., Gyawali, G., Lee, Y., Cho, J.-W., & Hur, J. (2022) · Chemosphere · doi:10.1016/j.chemosphere.2022.134320 · Cited by 81 · see citing works
Fortunato, G. V., Pizzutilo, E., Mingers, A. M., Kasian, O. I., Cherevko, S., Cardoso, E. S. F., Mayrhofer, K. J. J., Maia, G., & Ledendecker, M. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b04262 · Cited by 80 · see citing works
Active sites engineering of Pt/CNT oxygen reduction catalysts by atomic layer deposition
Gan, J., Zhang, J., Zhang, B., Chen, W., Niu, D., Qin, Y. H., Duan, X., & Zhou, X. (2019) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.09.024 · Cited by 80 · see citing works
Highly active zigzag-like Pt-Zn alloy nanowires with high-index facets for alcohol electrooxidation
Xu, Y., Cui, X., Wei, S., Zhang, Q., Gu, L., Meng, F., Fan, J., & Zheng, W. (2019) · Nano Research · doi:10.1007/s12274-019-2374-z · Cited by 78 · see citing works
Taming Electrons in Pt/C Catalysts to Boost the Mesokinetics of Hydrogen Production
Chen, W., Fu, W., Duan, X., Chen, B., Qian, G., Si, R., Zhou, X., Yuan, W., & Chen, D. (2022) · Engineering · doi:10.1016/j.eng.2020.11.014 · Cited by 78 · see citing works
Rao, R. G., Blume, R., Greiner, M. T., Liu, P., Hansen, T. W., Dreyer, K. S., Hibbitts, D. D., & Tessonnier, J. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c01063 · Cited by 78 · see citing works
Xie, M., Dai, F., Li, J., Dang, X., Guo, J., Lv, W., Zhang, Z., & Lu, X. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202103652 · Cited by 77 · see citing works
Interfacial engineering of platinum group metals electrocatalysts for advanced electrocatalysis
Li, J., Xu, Y., Wang, C., Wu, Z., Shiraishi, Y., & Du, Y. (2023) · Surfaces and Interfaces · doi:10.1016/j.surfin.2023.103360 · Cited by 75 · see citing works
Kumar, P. S. M., Ponnusamy, V. K., Deepthi, K. R., Kumar, G., Pugazhendhi, A., Abe, H., Thiripuranthagan, S., Pal, U., & Krishnan, S. K. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta07380e · Cited by 74 · see citing works
Won, J.-E., Kwak, D., Han, S.-B., Park, H.-S., Park, J., Ma, K.-B., Kim, D.-H., & Park, K. (2018) · Journal of Catalysis · doi:10.1016/j.jcat.2017.12.013 · Cited by 74 · see citing works
Sharma, M., Jung, N., & Yoo, S. J. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b03422 · Cited by 73 · see citing works
Escudero‐Escribano, M., Jensen, K. D., & Jensen, A. W. (2018) · Current Opinion in Electrochemistry · doi:10.1016/j.coelec.2018.04.013 · Cited by 73 · see citing works
Badam, R., Hara, M., Huang, H., & Yoshimura, M. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.08.034 · Cited by 73 · see citing works
Islam, J., Kim, S.-K., Thien, P. T., Kim, M., Cho, H., Cho, W. C., Kim, C., Lee, C., & Lee, J. H. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.230506 · Cited by 72 · see citing works
Confined Ultrafine Pt in Porous Carbon Fibers and Their N‑Enhanced Heavy d‑π Effect
Xiao, Y., Ying, J. R., Chen, J., Dong, Y., Yang, X., Tian, G., Wu, J., Janiak, C., Ozoemena, K. I., & Yang, X.-Y. (2022) · Chemistry of Materials · doi:10.1021/acs.chemmater.1c04400 · Cited by 66 · see citing works
Huang, C., Zhang, S., Wang, W., Zhou, H., Shao, Z., Xia, L., Wang, H., & Sun, Y. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c04608 · Cited by 66 · see citing works
Sang, K., Zuo, J., Zhang, X., Wang, Q., Chen, W., Qian, G., & Duan, X. (2022) · Green Energy & Environment · doi:10.1016/j.gee.2022.12.006 · Cited by 63 · see citing works
Wang, Y., Li, Z., Zheng, X., Wu, R. F., Song, J., Chen, Y., Cao, X., Wang, Y., & Nie, Y. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.122383 · Cited by 63 · see citing works
Quan, W., Shi, J., Zeng, M., Lv, W., Chen, X., Fan, C., Zhang, Y., Liu, Z., Huang, X., Yang, J., et al. (2024) · Nano-Micro Letters · doi:10.1007/s40820-024-01484-4 · Cited by 62 · see citing works
Nanostructure Optimization of Platinum-Based Nanomaterials for Catalytic Applications
Duan, S., Du, Z., Fan, H., & Wang, R. (2018) · Nanomaterials · doi:10.3390/nano8110949 · Cited by 62 · see citing works
Zhang, X., Sa, R., Yang, S., Zhou, F., Jiang, Z. R., & Wang, R. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.104981 · Cited by 61 · see citing works
Meng, G., Zhang, J., Li, X., Wang, D. S., & Li, Y. (2021) · Applied Physics Reviews · doi:10.1063/5.0048186 · Cited by 60 · see citing works
Synergistic electrocatalytic oxygen reduction reactions of Pd/B4C for ultra-stable Zn-air batteries
Chen, Y., Zhang, X., Cui, H., Zhang, X., Xie, Z., Wang, X., Jiao, M., & Zhou, Z. P. (2018) · Energy storage materials · doi:10.1016/j.ensm.2018.04.010 · Cited by 59 · see citing works
Molecular-level insights into the electronic effects in platinum-catalyzed carbon monoxide oxidation
Chen, W., Cao, J., Yang, J., Cao, Y., Zhang, H., Jiang, Z. R., Zhang, J., Qian, G., Zhou, X., Chen, D., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-27238-z · Cited by 58 · see citing works
Xu, C., Wu, Y., Li, S., Zhou, J., Chen, J., Jiang, M. H., Zhao, H., & Qin, G. W. (2019) · Journal of Material Science and Technology · doi:10.1016/j.jmst.2019.08.036 · Cited by 58 · see citing works
Anitha, V., Zazpe, R., Krbal, M., Yoo, J., Sopha, H., Přikryl, J., Cha, G., Šlang, S., Schmuki, P., & Macák, J. M. (2018) · Journal of Catalysis · doi:10.1016/j.jcat.2018.06.017 · Cited by 56 · see citing works
Liu, X., Wang, Y., Chen, L., Chen, P., Jia, S., Zhang, Y., Zhou, S., & Zang, J. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b13359 · Cited by 56 · see citing works
Pt/Mo2C heteronanosheets for superior hydrogen evolution reaction
Liu, Z., Li, J., Xue, S., Zhou, S., Qu, K., Li, Y., & Cai, W. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.02.005 · Cited by 56 · see citing works
Cheng, X., Xiao, B. J., Chen, Y., Wang, Y., Zheng, L., Lu, Y., Li, H., & Chen, G. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c00891 · Cited by 55 · see citing works
Rational design of noble metal-based multimetallic nanomaterials: A review
Yusuf, B. A., Yaseen, W., Xie, J., Babangida, A. A., Muhammad, A. I., Xie, M., & Xu, Y. (2022) · Nano Energy · doi:10.1016/j.nanoen.2022.107959 · Cited by 55 · see citing works
Wu, P., Jia, Q., He, J. H., Lu, L., Chen, L., Zhu, J., Peng, C., He, M., Xiong, J., Zhu, W., et al. (2020) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.122183 · Cited by 53 · see citing works
Harsha, S., Sharma, R. K., Dierner, M., Baeumer, C., Makhotkin, I. A., Mul, G., Ghigna, P., Spiecker, E., Will, J., & Altomare, M. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202403628 · Cited by 50 · see citing works
Liu, X., Wu, G., & Li, Q. (2024) · eScience · doi:10.1016/j.esci.2024.100270 · Cited by 49 · see citing works
The application and research progress of d-band center theory in the field of water electrolysis
Li, K., Tao, Z., Ma, X., Wu, J., Wu, T., Guo, C., Qi, Y., Yu, J., Zheng, J., & Xue, J. (2025) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2025.02.305 · Cited by 49 · see citing works
From metal to metal-free catalysts: Routes to sustainable chemistry
Monai, M., Melchionna, M., & Fornasiero, P. (2018) · Advances in catalysis · doi:10.1016/bs.acat.2018.10.001 · Cited by 49 · see citing works
Fang, H., Liao, C., Ying, Y., Cheng, J., Wang, Q., Huang, H., Luo, Y., & Jiang, L. (2022) · Journal of Catalysis · doi:10.1016/j.jcat.2022.11.028 · Cited by 47 · see citing works
Yoshii, T., Umemoto, D., Kuwahara, Y., Mori, K., & Yamashita, H. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b12470 · Cited by 47 · see citing works
Han, X., Chen, X., Zou, Y., & Zhang, S. M. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118451 · Cited by 47 · see citing works
Feng, W., Lei, Y., Wu, X., Yuan, J., Chen, J., Xu, D., Zhang, X., Zhang, S., Liu, P., Zhang, L., et al. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta09217g · Cited by 47 · see citing works
Progress and challenges of ceramics for supercapacitors
Zeng, X., Song, H., Shen, Z., & Moskovits, M. (2021) · Journal of Materiomics · doi:10.1016/j.jmat.2021.03.001 · Cited by 46 · see citing works
Zou, J., Duan, X., Liu, X., Huang, L., Liu, X., Zuo, J., Jiao, W., Lin, H., Ye, L., & Yuan, Y. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.140110 · Cited by 44 · see citing works
Hua, M., Song, J., Huang, X., Hou, M., Fan, H., Zhang, Z., Wu, T., & Han, B. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c00971 · Cited by 43 · see citing works
Jarvis, J., Harrhy, J. H., Wang, A., Bere, T., Morgan, D. J., Carter, J., Howe, A. G. R., He, Q., Hutchings, G. J., & Song, H. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c02361 · Cited by 42 · see citing works
Cheng, X., Lu, Y., Zheng, L., Pupucevski, M., Li, H., Chen, G., Sun, S., & Wu, G. (2021) · Materials Today Energy · doi:10.1016/j.mtener.2021.100653 · Cited by 42 · see citing works
Xiao, W.-Z., Xiao, L., Yang, Y., Zhai, S., & Sun, R. (2022) · Nano Research · doi:10.1007/s12274-022-4436-x · Cited by 40 · see citing works
Song, L., Liu, G., Jiang, X., & Qu, Z. (2025) · ACS Catalysis · doi:10.1021/acscatal.5c02948 · Cited by 40 · see citing works
Abnormal thermal stability of sub-10 nm Au nanoparticles and their high catalytic activity
Cao, X., Zhou, J., Wang, H., Li, S., Wang, W., & Qin, G. W. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta10515d · Cited by 40 · see citing works
Wang, C., Zhou, L., Liu, C., Qiao, J., Han, X., Wang, L., Liu, Y., Xu, B., Qiu, Q., Zhang, Z., et al. (2024) · Nature Communications · doi:10.1038/s41467-024-50557-w · Cited by 39 · see citing works
Mondal, S., & Raj, C. R. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b03840 · Cited by 39 · see citing works
Bhattacharyya, S. P., Samanta, D., Roy, S., Radhakantha, V. P. H., & Maji, T. K. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b20610 · Cited by 39 · see citing works
Chen, T., Xu, Y., Meng, D., Guo, X., Zhu, Y., Peng, L., Hu, J., & Ding, W. (2022) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2022.03.017 · Cited by 38 · see citing works
Krishnamurthy, C. B., Lori, O., Elbaz, L., & Grinberg, I. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b00949 · Cited by 36 · see citing works
Hua, E., Choi, S., Ren, S., Kim, S., Ali, G., Kim, S. J., Jang, W., Joo, S., Zhang, J., Ji, S., et al. (2023) · Energy & Environmental Science · doi:10.1039/d3ee01211e · Cited by 36 · see citing works
Kim, D., Ryou, K.-E., Park, G., Jung, S., Park, J., Kim, M., Jang, J., Song, M., Kim, S., Kim, J., et al. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.5c03118 · Cited by 35 · see citing works
Ullah, N., Odda, A. H., Liang, K., Kombo, M. A., Sahar, S., Ma, L.-B., Fang, X.-X., & Xu, A. (2019) · Green Chemistry · doi:10.1039/c8gc03440k · Cited by 35 · see citing works
Atomic ruthenium stabilized on vacancy-rich boron nitride for selective hydrogenation of esters
Huang, L., Liu, X., Zou, J., Duan, X., Chen, Z., Zhou, Z., Ye, L., Liang, X., Xie, S., & Yuan, Y. (2022) · Journal of Catalysis · doi:10.1016/j.jcat.2022.01.004 · Cited by 35 · see citing works
Brandiele, R., Zerbetto, M., Dalconi, M. C., Rizzi, G. A., Isse, A. A., Durante, C., & Gennaro, A. (2019) · ChemSusChem · doi:10.1002/cssc.201901568 · Cited by 35 · see citing works
Zeng, Z., Yi, L., He, J., Hu, Q. Y., Liao, Y., Wang, Y., Luo, W., & Pan, M. (2020) · Journal of Materials Science · doi:10.1007/s10853-019-04327-5 · Cited by 35 · see citing works
Porkovich, A. J., Ziadi, Z., Kumar, P., Kioseoglou, J., Jian, N., Weng, L., Steinhauer, S., Vernieres, J., Grammatikopoulos, P., & Sowwan, M. (2019) · ACS Nano · doi:10.1021/acsnano.9b06224 · Cited by 34 · see citing works
Fermi Level Equilibration and Charge Transfer at the Exsolved Metal-Oxide Interface
Wang, J., Yang, J., Wardini, J. L., Waluyo, I., Hunt, A. H., Crumlin, E. J., Fairley, N., Bowman, W. J., Hwang, H. Y., & Yildiz, B. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.4c14695 · Cited by 32 · see citing works
Haq, T. U., Arooj, M., Tahir, A., & Haik, Y. (2023) · Small · doi:10.1002/smll.202305694 · Cited by 31 · see citing works
- Authors
- Jackson, C., Smith, G. T., Inwood, D. W., Leach, A. S., Whalley, P. S., Callisti, M., Polcar, T., Russell, A. E., Levecque, P., & Kramer, D.
- Affiliations
- University of Cape Town (ZA)
- University of Southampton (GB)
- Corresponding author
- Kramer, Denis
- ORCID
- Venue
- Nature Communications
- Published
- 2017-06-22
- Volume
- 8
- Issue
- 1
- Pages
- 15802-15802
- ISSN
- 2041-1723 (ISSN-L)
- PMC
- PMC5489685
- OpenAlex
- W2618879542
- Cited by
- 231
- References
- 70
- Citations by year
- 2026: 16 · 2025: 28 · 2024: 22 · 2023: 25 · 2022: 34 · 2021: 26 · 2020: 28 · 2019: 27 · 2018: 21 · 2017: 4
- FWCI
- 5.86
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Nature Communications (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- ePrints Soton (University of Southampton) (acceptedVersion, cc-by)
- RePEc: Research Papers in Economics (submittedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Spiral (Imperial College London) (submittedVersion, cc-by)
- Funders
- Diamond Light Source
- Royal Society (NA140367)
- Newcastle University
- Paul Scherrer Institut
- University of Cape Town
- Engineering and Physical Sciences Research Council (EP/J016454/1, EP/F034296/1, EP/K040375/1, EP/J013501/1, EP/J016454/)
- Science and Technology Facilities Council (ST/N002385/1, ST/K00171X/1)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Keywords
- oxygen reduction reaction, platinum nanoparticles, metal-support interaction, electronic structure, electrocatalyst stability, acidic media, platinum alloying
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