The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission
Open accessAbstract
Coordinative immobilization of functionalized tetraphenylethylene within rigid porous metal-organic frameworks (MOFs) turns on fluorescence in the typically non-emissive tetraphenylethylene core. The matrix coordination-induced emission effect (MCIE) is complementary to aggregation-induced emission. Despite the large interchromophore distances imposed by coordination to metal ions, a carboxylate analogue of tetraphenylethylene anchored by Zn(2+) and Cd(2+) ions inside MOFs shows fluorescence lifetimes in line with those of close-packed molecular aggregates. Turn-on fluorescence by coordinative ligation in a porous matrix is a powerful approach that may lead to new materials made from chromophores with molecular rotors. The potential utility of MCIE toward building new sensing materials is demonstrated by tuning the fluorescence response of the porous MOFs as a function of adsorbed small analytes.
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Cites
Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole
Luo, J., Xie, Z., Lam, J. W. Y., Cheng, L., Tang, B. Z., Chen, H., Qiu, C., Kwok, H. S., Zhan, X., Liu, Y., et al. (2001) · Chemical Communications · doi:10.1039/b105159h · Cited by 8,358
Hong, Y., Lam, J. W. Y., & Tang, B. Z. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15113d · Cited by 6,363
Cited by
Aggregation-Induced Emission: Together We Shine, United We Soar!
Mei, J., Leung, N. L. C., Kwok, R. T. K., Lam, J. W. Y., & Tang, B. Z. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00263 · Cited by 8,270
Luminescent sensors based on metal-organic frameworks
Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Highly emissive platinum(II) metallacages
Yan, X., Cook, T. R., Wang, P., Huang, F., & Stang, P. J. (2015) · Nature Chemistry · doi:10.1038/nchem.2201 · Cited by 678
Wang, J., Mei, J., Hu, R., Sun, J. Z., Qin, A., & Tang, B. Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja208883h · Cited by 593
Piezofluorochromic Metal–Organic Framework: A Microscissor Lift
Zhang, Q., Su, J., Feng, D., Wei, Z., Zou, X., & Zhou, H.-C. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04695 · Cited by 272
Metadata
- Authors
- Shustova, N. B., McCarthy, B. D., & Dincă, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-11-22
- Volume
- 133
- Issue
- 50
- Pages
- 20126-20129
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2077741286
- Cited by
- 733
- References
- 2
- FWCI
- 20.06
- Type
- journal article
- Language
- en
- Open access
- green
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- Shustova, N. B., McCarthy, B. D., & Dincă, M. (2011). Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission. Journal of the American Chemical Society. https://doi.org/10.1021/ja209327q
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