The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Effect of the TiO2 Reduction State on the Catalytic CO Oxidation on Deposited Size-Selected Pt Clusters
Open accessAbstract
The catalytic activity of deposited Pt(7) clusters has been studied as a function of the reduction state of the TiO(2)(110)-(1 × 1) support for the CO oxidation reaction. While a slightly reduced support gives rise to a high catalytic activity of the adparticles, a strongly reduced one quenches the CO oxidation. This quenching is due to thermally activated diffusion of Ti(3+) interstitials from the bulk to the surface where they deplete the oxygen adsorbed onto the clusters by the formation of TiO(x) (x ≃ 2) structures. This reaction is more rapid than the CO oxidation. The present results are of general relevance to heterogeneous catalysis on TiO(2)-supported metal clusters and for reactions involving oxygen as intermediate.
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Cites
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Tauster, S. J., Fung, S. C., & Garten, R. L. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00469a029 · Cited by 3,188
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au 8 Clusters on MgO
Yoon, B., Häkkinen, H., Landman, U., Wörz, A. S., Antonietti, J.-M., Abbet, S., Judai, K., & Heiz, U. (2005) · Science · doi:10.1126/science.1104168 · Cited by 1,430
Cited by
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles
Liu, L., & Corma, A. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00776 · Cited by 4,777
Synthetic strategies of supported atomic clusters for heterogeneous catalysis
Rong, H., Ji, S., Zhang, J., Wang, D., & Li, Y. (2020) · Nature Communications · doi:10.1038/s41467-020-19571-6 · Cited by 367
Gomathi Devi, L., & Kavitha, R. (2016) · Applied Surface Science · doi:10.1016/j.apsusc.2015.11.016 · Cited by 359
Catalysis Applications of Size-Selected Cluster Deposition
Vajda, S., & White, M. G. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01816 · Cited by 293
Metadata
- Authors
- Bonanni, S., Aït-Mansour, K., Harbich, W., & Brune, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-02-02
- Volume
- 134
- Issue
- 7
- Pages
- 3445-3450
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2003496331
- Cited by
- 158
- References
- 3
- FWCI
- 7.67
- Type
- journal article
- Language
- en
- Open access
- green
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