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Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles

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Liu, Lichen, Corma, Avelino·2018·Chemical Reviews
DOI 10.1021/acs.chemrev.7b00776
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Abstract

Metal species with different size (single atoms, nanoclusters, and nanoparticles) show different catalytic behavior for various heterogeneous catalytic reactions. It has been shown in the literature that many factors including the particle size, shape, chemical composition, metal-support interaction, and metal-reactant/solvent interaction can have significant influences on the catalytic properties of metal catalysts. The recent developments of well-controlled synthesis methodologies and advanced characterization tools allow one to correlate the relationships at the molecular level. In this Review, the electronic and geometric structures of single atoms, nanoclusters, and nanoparticles will be discussed. Furthermore, we will summarize the catalytic applications of single atoms, nanoclusters, and nanoparticles for different types of reactions, including CO oxidation, selective oxidation, selective hydrogenation, organic reactions, electrocatalytic, and photocatalytic reactions. We will compare the results obtained from different systems and try to give a picture on how different types of metal species work in different reactions and give perspectives on the future directions toward better understanding of the catalytic behavior of different metal entities (single atoms, nanoclusters, and nanoparticles) in a unifying manner.

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Metadata

Authors
Liu, L., & Corma, A.
Venue
Chemical Reviews
Publisher
American Chemical Society (ACS)
Published
2018-04-16
Volume
118
Issue
10
Pages
4981-5079
ISSN
  • 0009-2665 (ISSN-L)
  • 1520-6890
DOI
10.1021/acs.chemrev.7b00776
OpenAlex
W2802791016
Cited by
4,777
References
22
FWCI
16.09
Type
journal article
Language
en
Open access
hybrid
Licence
pubs.acs.org/page/policy/authorchoice_termsofuse.html (vor, 100 d)
Funders
  • H2020 European Research Council (671093)
  • Ministerio de Economía, Industria y Competitividad (SEV-2016-0683)

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Liu, L., & Corma, A. (2018). Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.7b00776

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