The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Selective Modification of Halloysite Lumen with Octadecylphosphonic Acid: New Inorganic Tubular Micelle
Abstract
Selective fatty acid hydrophobization of the inner surface of tubule halloysite clay is demonstrated. Aqueous phosphonic acid was found to bind to alumina sites at the tube lumen and did not bind the tube's outer siloxane surface. The bonding was characterized with solid-state nuclear magnetic resonance ((29)Si, (13)C, (31)P NMR), Fourier transform infrared (FTIR), and X-ray photoelectron spectroscopy. NMR and FTIR spectroscopy of selectively modified tubes proved binding of octadecylphosphonic acid within the halloysite lumen through bidentate and tridentate P-O-Al linkage. Selective modification of the halloysite clay lumen creates an inorganic micelle-like architecture with a hydrophobic aliphatic chain core and a hydrophilic silicate shell. An enhanced capacity for adsorption of the modified halloysite toward hydrophobic derivatives of ferrocene was shown. This demonstrates that the different inner and outer surface chemistry of clay nanotubes can be used for selective modification, enabling different applications from water purification to drug immobilization and controlled release.
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Citations
Cites
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Cited by
Halloysite Clay Nanotubes for Loading and Sustained Release of Functional Compounds
Lvov, Y., Wang, W., Zhang, L., & Fakhrullin, R. (2016) · Advanced Materials · doi:10.1002/adma.201502341 · Cited by 990
Self-citationCovalent Surface Modification of Oxide Surfaces
Pujari, S. P., Scheres, L., Marcelis, A. T. M., & Zuilhof, H. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201306709 · Cited by 934
Functional polymer–clay nanotube composites with sustained release of chemical agents
Lvov, Y., & Abdullayev, E. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2013.05.009 · Cited by 572
Self-citationZhang, W., Taheri-Ledari, R., Ganjali, F., Afruzi, F. H., Hajizadeh, Z., Saeidirad, M., Qazi, F. S., Kashtiaray, A., Sehat, S. S., Hamblin, M. R., et al. (2022) · Heliyon · doi:10.1016/j.heliyon.2022.e09577 · Cited by 79
Retracted
Metadata
- Authors
- Yah, W. O., Takahara, A., & Lvov, Y. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-01-12
- Volume
- 134
- Issue
- 3
- Pages
- 1853-1859
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2322518459
- Cited by
- 429
- References
- 38
- FWCI
- 8.89
- Type
- journal article
- Language
- en
- Open access
- closed
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