The DOI matches its Crossref record; 20 of the 20 references it cites were found in a registry or an index.
Guest-to-Host Transmission of Structural Changes for Stimuli-Responsive Adsorption Property
Abstract
We show that structural changes of a guest molecule can trigger structural transformations of a crystalline host framework. Azobenzene was introduced into a flexible porous coordination polymer (PCP), and cis/trans isomerizations of the guest azobenzene by light or heat successfully induced structural transformations of the host PCP in a reversible fashion. This guest-to-host structural transmission resulted in drastic changes in the gas adsorption property of the host-guest composite, displaying a new strategy for creating stimuli-responsive porous materials.
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Citations
Cites
Functional Porous Coordination Polymers
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Self-citationReticular synthesis and the design of new materials
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Self-citationPostsynthetic modification of metal–organic frameworks
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Mechanical twisting of a guest by a photoresponsive host
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Self-citationFunctional Mixed Metal–Organic Frameworks with Metalloligands
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The first porous MOF with photoswitchable linker molecules
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Topotactic Linear Radical Polymerization of Divinylbenzenes in Porous Coordination Polymers
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Self-citationVisual Rhodopsin Sees the Light: Structure and Mechanism of G Protein Signaling
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Reversible Photoswitching Liquid-phase Adsorption on Azobenzene Derivative-grafted Mesoporous Silica
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Cited by
Coudert, F.-X. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b00046 · Cited by 528
Gating effect for gas adsorption in microporous materials—mechanisms and applications
Chen, K., Mousavi, S. H., Singh, R., Snurr, R. Q., Li, G., & Webley, P. A. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00822f · Cited by 133
Metadata
- Authors
- Yanai, N., Uemura, T., Inoue, M., Matsuda, R., Fukushima, T., Tsujimoto, M., Isoda, S., & Kitagawa, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-03-01
- Volume
- 134
- Issue
- 10
- Pages
- 4501-4504
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2318957155
- Cited by
- 369
- References
- 20
- FWCI
- 16.61
- Type
- journal article
- Language
- en
- Open access
- closed
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