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Cited by 349

The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.

A Chiral Quadruple-Stranded Helicate Cage for Enantioselective Recognition and Separation

Xuan, Weimin, Zhang, Mengni, Liu, Yan, Chen, Zhijie, Cui, Yong·2012·Journal of the American Chemical Society

Abstract

The self-assembly of enantiopure pyridyl-functionalized metallosalan units affords a homochiral helicate cage, [Zn(8)L(4)Cl(8)], in which the optical rotation of each ligand is increased by a factor of 10 upon coordination. The octanuclear cage featuring a chiral amphiphilic cavity exhibits enantioselective luminescence enhancement by amino acids in solution. The cage exists in two different crystalline polymorphic forms that possess porous structures built of helicate cages interconnected by 1D channels or pentahedral cages and have the ability to separate small racemic molecules by adsorption but with different enantioselectivities.

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Crossref · 10.1021/ja212132r

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Metadata

Authors
Xuan, W., Zhang, M., Liu, Y., Chen, Z., & Cui, Y.
Venue
Journal of the American Chemical Society
Published
2012-04-11
Volume
134
Issue
16
Pages
6904-6907
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1968649101
Cited by
349
References
30
FWCI
16.62
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Chiral Quadruple-Stranded Helicate Cage for Enantioselective Recognition and Separation. https://app.cochat.ai/papers/10.1021/ja212132r
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Xuan, W., Zhang, M., Liu, Y., Chen, Z., & Cui, Y. (2012). A Chiral Quadruple-Stranded Helicate Cage for Enantioselective Recognition and Separation. Journal of the American Chemical Society. https://doi.org/10.1021/ja212132r

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.