The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Effect of Nature and Location of Defects on Bandgap Narrowing in Black TiO2Nanoparticles
Abstract
The increasing need for new materials capable of solar fuel generation is central in the development of a green energy economy. In this contribution, we demonstrate that black TiO(2) nanoparticles obtained through a one-step reduction/crystallization process exhibit a bandgap of only 1.85 eV, which matches well with visible light absorption. The electronic structure of black TiO(2) nanoparticles is determined by the unique crystalline and defective core/disordered shell morphology. We introduce new insights that will be useful for the design of nanostructured photocatalysts for energy applications.
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Cites
Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Cited by
Wang, Z., Yang, C., Lin, T., Yin, H., Chen, P., Wan, D., Xu, F., Huang, F., Lin, J., Xie, X., et al. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201300486 · Cited by 719
Zheng, Q., Chu, W., Zhao, C., Zhang, L., Guo, H., Wang, Y., Jiang, X., & Zhao, J. (2019) · WIREs Computational Molecular Science · doi:10.1002/wcms.1411 · Cited by 452
Vacancies in functional materials for clean energy storage and harvesting: the perfect imperfection
Li, G., Blake, G. R., & Palstra, T. T. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00571c · Cited by 336
Wu, Z., Yang, P., Li, Q., Xiao, W., Li, Z., Xu, G., Liu, F., Jia, B., Ma, T., Feng, S., et al. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202300406 · Cited by 226
Chen, X., Zhao, D., Liu, K., Wang, C., Liu, L., Li, B., Zhang, Z., & Shen, D. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b04568 · Cited by 147
Metadata
- Authors
- Naldoni, A., Allieta, M., Santangelo, S., Marelli, M., Fabbri, F., Cappelli, S., Bianchi, C. L., Psaro, R., & Dal Santo, V.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-24
- Volume
- 134
- Issue
- 18
- Pages
- 7600-7603
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2333197797
- Cited by
- 1,675
- References
- 1
- FWCI
- 32.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Naldoni, A., Allieta, M., Santangelo, S., Marelli, M., Fabbri, F., Cappelli, S., Bianchi, C. L., Psaro, R., & Dal Santo, V. (2012). Effect of Nature and Location of Defects on Bandgap Narrowing in Black TiO2Nanoparticles. Journal of the American Chemical Society. https://doi.org/10.1021/ja3012676
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