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Effect of Nature and Location of Defects on Bandgap Narrowing in Black TiO2Nanoparticles
Abstract
The increasing need for new materials capable of solar fuel generation is central in the development of a green energy economy. In this contribution, we demonstrate that black TiO(2) nanoparticles obtained through a one-step reduction/crystallization process exhibit a bandgap of only 1.85 eV, which matches well with visible light absorption. The electronic structure of black TiO(2) nanoparticles is determined by the unique crystalline and defective core/disordered shell morphology. We introduce new insights that will be useful for the design of nanostructured photocatalysts for energy applications.
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Citations
Cites
Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
Cited by
Engineering heterogeneous semiconductors for solar water splitting
Li, X., Yu, J., Low, J., Fang, Y., Xiao, J., & Chen, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04461d · Cited by 1,888
Defect engineering in photocatalytic materials
Bai, S., Zhang, N., Gao, C., & Xiong, Y. (2018) · Nano Energy · doi:10.1016/j.nanoen.2018.08.058 · Cited by 1,236
Recent Progress in Energy‐Driven Water Splitting
Tee, S. Y., Win, K. Y., Teo, W. S., Koh, L., Liu, S., Teng, C. P., & Han, M. (2017) · Advanced Science · doi:10.1002/advs.201600337 · Cited by 962
Khan, M. M., Ansari, S. A., Pradhan, D., Ansari, M. O., Han, D. H., Lee, J., & Cho, M. H. (2014) · J. Mater. Chem. A · doi:10.1039/c3ta14052k · Cited by 888
Li, L., Yan, J., Wang, T., Zhao, Z.-J., Zhang, J., Gong, J., & Guan, N. (2015) · Nature Communications · doi:10.1038/ncomms6881 · Cited by 847
Photocatalysis with Reduced TiO2: From Black TiO2 to Cocatalyst-Free Hydrogen Production
Naldoni, A., Altomare, M., Zoppellaro, G., Liu, N., Kment, Š., Zbořil, R., & Schmuki, P. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04068 · Cited by 770
Self-citationWang, Z., Yang, C., Lin, T., Yin, H., Chen, P., Wan, D., Xu, F., Huang, F., Lin, J., Xie, X., et al. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201300486 · Cited by 719
Wang, S., Pan, L., Song, J.-J., Mi, W., Zou, J.-J., Wang, L., & Zhang, X. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512047k · Cited by 718
Yan, J., Wu, G., Guan, N., Li, L., Li, Z., & Cao, X. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp50927c · Cited by 684
Progress in Developing Metal Oxide Nanomaterials for Photoelectrochemical Water Splitting
Yang, Y., Niu, S., Han, D., Liu, T., Wang, G., & Li, Y. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700555 · Cited by 655
Jiang, X., Zhang, Y., Jiang, J., Rong, Y., Wang, Y., Wu, Y., & Pan, C. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp307573c · Cited by 585
Reduced TiO2 nanotube arrays for photoelectrochemical water splitting
Kang, Q., Cao, J., Zhang, Y., Liu, L., Xu, H., & Ye, J. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta10689f · Cited by 584
Hydrogenated TiO2 Nanocrystals: A Novel Microwave Absorbing Material
Xia, T., Zhang, C., Oyler, N. A., & Chen, X. (2013) · Advanced Materials · doi:10.1002/adma.201303088 · Cited by 559
Li, J., Zhang, M., Guan, Z., Li, Q., He, C., & Yang, J. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.01.025 · Cited by 503
Black TiO2 Nanotubes: Cocatalyst-Free Open-Circuit Hydrogen Generation
Liu, N., Schneider, C., Freitag, D., Hartmann, M., Venkatesan, U., Müller, J., Spiecker, E., & Schmuki, P. (2014) · Nano Letters · doi:10.1021/nl500710j · Cited by 462
Zheng, Q., Chu, W., Zhao, C., Zhang, L., Guo, H., Wang, Y., Jiang, X., & Zhao, J. (2019) · WIREs Computational Molecular Science · doi:10.1002/wcms.1411 · Cited by 452
Huang, J., Xie, Y., You, Y., Yuan, J., Xu, Q., Xie, H., & Chen, Y. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202213095 · Cited by 448
Han, X., Huang, J., Jing, X., Yang, D., Lin, H., Wang, Z., Li, P., & Chen, Y. (2018) · ACS Nano · doi:10.1021/acsnano.8b00899 · Cited by 437
Ye, M., Jia, J., Wu, Z., Qian, C., Chen, R., O'Brien, P. G., Sun, W., Dong, Y., & Ozin, G. A. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601811 · Cited by 417
Role of oxygen vacancy in metal oxides for photocatalytic CO2 reduction
Jiang, W., Loh, H., Low, B. Q. L., Zhu, H., Low, J., Heng, J. Z. X., Tang, K. Y., Li, Z., Loh, X. J., Ye, E., et al. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.122079 · Cited by 401
Surface oxygen vacancies on Co3O4 mediated catalytic formaldehyde oxidation at room temperature
Wang, Z., Wang, W., Zhang, L., & Jiang, D. (2016) · Catalysis Science & Technology · doi:10.1039/c5cy01709b · Cited by 386
Ultrathin S-doped MoSe2nanosheets for efficient hydrogen evolution
Xu, C., Peng, S., Tan, C., Ang, H., Tan, H., Zhang, H., & Yan, Q. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta00458b · Cited by 366
Oxygen defective metal oxides for energy conversion and storage
Wang, G., Yang, Y., Han, D., & Li, Y. (2017) · Nano Today · doi:10.1016/j.nantod.2017.02.009 · Cited by 353
Photocatalytic water splitting for solar hydrogen generation: fundamentals and recent advancements
Yuan, L., Han, C., Yang, M.-Q., & Xu, Y.-J. (2016) · International Reviews in Physical Chemistry · doi:10.1080/0144235x.2015.1127027 · Cited by 351
Broadband Hot‐Electron Collection for Solar Water Splitting with Plasmonic Titanium Nitride
Naldoni, A., Guler, U., Wang, Z., Marelli, M., Malara, F., Meng, X., Besteiro, L. V., Govorov, A. O., Kildishev, A. V., Boltasseva, A., et al. (2017) · Advanced Optical Materials · doi:10.1002/adom.201601031 · Cited by 344
Self-citationVacancies in functional materials for clean energy storage and harvesting: the perfect imperfection
Li, G., Blake, G. R., & Palstra, T. T. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00571c · Cited by 336
Black TiO2: A review of its properties and conflicting trends
Rajaraman, T. S., Parikh, S. P., & Gandhi, V. G. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.123918 · Cited by 323
Kumar, A., & Krishnan, V. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202009807 · Cited by 323
Photocatalytic nitrogen fixation: the role of defects in photocatalysts
Cheng, M., Xiao, C., & Xie, Y. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta06435d · Cited by 319
Zafar, Z., Yi, S., Li, J., Li, C., Zhu, Y., Zada, A., Yao, W., Liu, Z., & Yue, X. (2022) · ENERGY & ENVIRONMENTAL MATERIALS · doi:10.1002/eem2.12171 · Cited by 284
Gupta, T., Samriti, Cho, J., & Prakash, J. (2021) · Materials Today Chemistry · doi:10.1016/j.mtchem.2021.100428 · Cited by 268
Khan, H., & Shah, M. U. H. (2023) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2023.111532 · Cited by 267
Luo, Z., Poyraz, A. S., Kuo, C.-H., Miao, R., Meng, Y., Chen, S.-Y., Jiang, T., Wenos, C., & Suib, S. L. (2015) · Chemistry of Materials · doi:10.1021/cm5035112 · Cited by 264
Xin, X., Xu, T., Yin, J., Wang, L., & Wang, C. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.04.016 · Cited by 261
Wu, Z., Yang, P., Li, Q., Xiao, W., Li, Z., Xu, G., Liu, F., Jia, B., Ma, T., Feng, S., et al. (2023) · Angewandte Chemie International Edition · doi:10.1002/anie.202300406 · Cited by 226
Chen, X., Zhao, D., Liu, K., Wang, C., Liu, L., Li, B., Zhang, Z., & Shen, D. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b04568 · Cited by 147
Li, B., Zhao, Z., Zhou, Q., Meng, B., Meng, X., & Qiu, J. (2014) · Chemistry – A European Journal · doi:10.1002/chem.201402664 · Cited by 95
Eco-Friendly Heterogeneous Photocatalysis on Biochar-Based Materials Under Solar Irradiation
Matos, J. (2016) · Topics in Catalysis · doi:10.1007/s11244-015-0434-5 · Cited by 31
Aerogels-Inspired based Photo and Electrocatalyst for Water Splitting to Produce Hydrogen
Al-Hamamre, Z., Karimzadeh, Z., Ji, S., Choi, H., & Maleki, H. (2022) · Applied Materials Today · doi:10.1016/j.apmt.2022.101670 · Cited by 18
Metadata
- Authors
- Naldoni, A., Allieta, M., Santangelo, S., Marelli, M., Fabbri, F., Cappelli, S., Bianchi, C. L., Psaro, R., & Dal Santo, V.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-04-24
- Volume
- 134
- Issue
- 18
- Pages
- 7600-7603
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2333197797
- Cited by
- 1,675
- References
- 2
- FWCI
- 32.31
- Type
- journal article
- Language
- en
- Open access
- closed
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