The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Chiral Nanoporous Metal–Metallosalen Frameworks for Hydrolytic Kinetic Resolution of Epoxides
Abstract
Chiral nanoporous metal-organic frameworks are constructed by using dicarboxyl-functionalized chiral Ni(salen) and Co(salen) ligands. The Co(salen)-based framework is shown to be an efficient and recyclable heterogeneous catalyst for hydrolytic kinetic resolution (HKR) of racemic epoxides with up to 99.5% ee. The MOF structure brings Co(salen) units into a highly dense arrangement and close proximity that enhances bimetallic cooperative interactions, leading to improved catalytic activity and enantioselectivity in HKR compared with its homogeneous analogues, especially at low catalyst/substrate ratios.
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Cites
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Self-citationLuminescent metal–organic frameworks
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Cited by
Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications
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Chiral Metal–Organic Frameworks
Gong, W., Chen, Z., Dong, J., Liu, Y., & Cui, Y. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00740 · Cited by 579
Self-citationBioinspired Framework Catalysts: From Enzyme Immobilization to Biomimetic Catalysis
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Self-citationChiral covalent organic frameworks: design, synthesis and property
Han, X., Yuan, C., Hou, B., Liu, L., Li, H., Liu, Y., & Cui, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00009d · Cited by 478
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Engineering chiral porous metal-organic frameworks for enantioselective adsorption and separation
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Metadata
- Authors
- Zhu, C., Yuan, G., Chen, X., Yang, Z., & Cui, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-05-02
- Volume
- 134
- Issue
- 19
- Pages
- 8058-8061
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2332253101
- Cited by
- 257
- References
- 45
- FWCI
- 14.87
- Type
- journal article
- Language
- en
- Open access
- closed
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