The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Interplay of Metalloligand and Organic Ligand to Tune Micropores within Isostructural Mixed-Metal Organic Frameworks (M′MOFs) for Their Highly Selective Separation of Chiral and Achiral Small Molecules
Open accessAbstract
Four porous isostructural mixed-metal-organic frameworks (M'MOFs) have been synthesized and structurally characterized. The pores within these M'MOFs are systematically tuned by the interplay of both the metalloligands and organic ligands which have enabled us not only to direct their highly selective separation of chiral alcohols 1-phenylethanol (PEA), 2-butanol (BUT), and 2-pentanol (2-PEN) with the highest ee up to 82.4% but also to lead highly selective separation of achiral C(2)H(2)/C(2)H(4) separation. The potential application of these M'MOFs for the fixed bed pressure swing adsorption (PSA) separation of C(2)H(2)/C(2)H(4) has been further examined and compared by the transient breakthrough simulations in which the purity requirement of 40 ppm in the outlet gas can be readily fulfilled by the fixed bed M'MOF-4a adsorber at ambient conditions.
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Cites
Large-scale screening of hypothetical metal–organic frameworks
Wilmer, C. E., Leaf, M., Lee, C. Y., Farha, O. K., Hauser, B. G., Hupp, J. T., & Snurr, R. Q. (2012) · Nature Chemistry · doi:10.1038/nchem.1192 · Cited by 1,439
Cited by
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene
Cui, X., Chen, K., Xing, H., Yang, Q., Krishna, R., Bao, Z., Wu, H., Zhou, W., Dong, X., Han, Y., et al. (2016) · Science · doi:10.1126/science.aaf2458 · Cited by 1,449
Self-citationMetal–Organic Frameworks for Separation
Zhao, X., Wang, Y., Li, D., Bu, X., & Feng, P. (2018) · Advanced Materials · doi:10.1002/adma.201705189 · Cited by 1,305
Porous metal-organic frameworks for gas storage and separation: Status and challenges
Li, H., Li, L., Lin, R.-B., Zhou, W., Zhang, Z., Xiang, S., & Chen, B. (2019) · EnergyChem · doi:10.1016/j.enchem.2019.100006 · Cited by 891
Self-citationYang, L., Qian, S., Wang, X., Cui, X., Chen, B., & Xing, H. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00756c · Cited by 746
Self-citationHe, Y., Krishna, R., & Chen, B. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22858k · Cited by 674
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Metadata
- Authors
- Das, M. C., Guo, Q., He, Y., Kim, J., Zhao, C.-G., Hong, K., Xiang, S., Zhang, Z., Thomas, K. M., Krishna, R., & Chen, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-05-11
- Volume
- 134
- Issue
- 20
- Pages
- 8703-8710
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2004235923
- Cited by
- 354
- References
- 1
- FWCI
- 21.33
- Type
- journal article
- Language
- en
- Open access
- green
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