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Pillar[6]arene-Based Photoresponsive Host–Guest Complexation
Abstract
The trans form of an azobenzene-containing guest can complex with a pillar[6]arene, while it cannot complex with pillar[5]arenes due to the different cavity sizes of the pillar[6]arene and the pillar[5]arenes. The spontaneous aggregation of its host-guest complex with the pillar[6]arene can be reversibly photocontrolled by irradiation with UV and visible light, leading to a switch between irregular aggregates and vesicle-like aggregates. This new pillar[6]arene-based photoresponsive host-guest recognition motif can work in organic solvents and is a good supplement to the existing widely used cyclodextrin/azobenzene recognition motif.
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Citations
Cited by
Xia, D., Wang, P., Ji, X., Khashab, N. M., Sessler, J. L., & Huang, F. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00839 · Cited by 734
Self-citationCharacterization of supramolecular gels
Yu, G., Yan, X., Han, C., & Huang, F. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60080g · Cited by 626
Self-citationYu, G., Zhou, X., Zhang, Z., Han, C., Mao, Z., Gao, C., & Huang, F. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3099905 · Cited by 486
Self-citationCao, Y., Hu, X.-Y., Li, Y., Zou, X., Xiong, S., Lin, C., Shen, Y.-Z., & Wang, L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505344t · Cited by 339
Mimicking the Cell: Bio-Inspired Functions of Supramolecular Assemblies
Tu, Y., Peng, F., Adawy, A., Men, Y., Abdelmohsen, L. K. E. A., & Wilson, D. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00344 · Cited by 316
Metadata
- Authors
- Yu, G., Han, C., Zhang, Z., Chen, J., Yan, X., Zheng, B., Liu, S., & Huang, F.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-05-08
- Volume
- 134
- Issue
- 20
- Pages
- 8711-8717
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2319589952
- Cited by
- 481
- References
- 0
- FWCI
- 28.58
- Type
- journal article
- Language
- en
- Open access
- closed
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