The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.
Catalytic Asymmetric α-Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N-Heterocyclic Carbene and Photoredox Catalysis
Open accessAbstract
Cross-coupling reactions are among the most widely utilized methods for C-C bond formation; however, the requirement of preactivated starting materials still presents a major limitation. Methods that take direct advantage of the inherent reactivity of the C-H bond offer an efficient alternative to these methods, negating the requirement for substrate preactivation. In this process, two chemically distinct activation events culminate in the formation of the desired C-C bond with loss of H(2) as the only byproduct. Herein we report the catalytic asymmetric α-acylation of tertiary amines with aldehydes facilitated by the combination of chiral N-heterocyclic carbene catalysis and photoredox catalysis.
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Cites
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Cited by
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Metadata
- Authors
- DiRocco, D. A., & Rovis, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-05-02
- Volume
- 134
- Issue
- 19
- Pages
- 8094-8097
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2334373491
- Cited by
- 573
- References
- 14
- FWCI
- 26.10
- Type
- journal article
- Language
- en
- Open access
- green
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