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Cited by 236

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Dramatic Enhancement of CO2 Uptake by Poly(ethyleneimine) Using Zirconosilicate Supports

Kuwahara, Yasutaka, Kang, Dun-Yen, Copeland, John R., Brunelli, Nicholas A., Didas, Stephanie A., Bollini, Praveen, Sievers, Carsten, Kamegawa, Takashi, Yamashita, Hiromi, Jones, Christopher W.·2012·Journal of the American Chemical Society

Abstract

The CO(2) adsorption characteristics of prototypical poly(ethyleneimine)/silica composite adsorbents can be drastically enhanced by altering the acid/base properties of the oxide support via incorporation of Zr into the silica support. Introduction of an optimal amount of Zr resulted in a significant improvement in the CO(2) capacity and amine efficiency under dilute (simulated flue gas) and ultradilute (simulated ambient air) conditions. Adsorption experiments combined with detailed characterization by thermogravimetric analysis, temperature-programmed desorption, and in situ FT-IR spectroscopy clearly demonstrate a stabilizing effect of amphoteric Zr sites that enhances the adsorbent capacity, regenerability, and stability over continued recycling. It is suggested that the important role of the surface properties of the oxide support in these polymer/oxide composite adsorbents has been largely overlooked and that the properties may be even further enhanced in the future by tuning the acid/base properties of the support.

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Metadata

Authors
Kuwahara, Y., Kang, D.-Y., Copeland, J. R., Brunelli, N. A., Didas, S. A., Bollini, P., Sievers, C., Kamegawa, T., Yamashita, H., & Jones, C. W.
Venue
Journal of the American Chemical Society
Published
2012-06-20
Volume
134
Issue
26
Pages
10757-10760
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2329367218
Cited by
236
References
1
FWCI
39.69
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Dramatic Enhancement of CO2 Uptake by Poly(ethyleneimine) Using Zirconosilicate Supports. https://app.cochat.ai/papers/10.1021/ja303136e
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Kuwahara, Y., Kang, D.-Y., Copeland, J. R., Brunelli, N. A., Didas, S. A., Bollini, P., Sievers, C., Kamegawa, T., Yamashita, H., & Jones, C. W. (2012). Dramatic Enhancement of CO2 Uptake by Poly(ethyleneimine) Using Zirconosilicate Supports. Journal of the American Chemical Society. https://doi.org/10.1021/ja303136e

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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