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Dramatic Enhancement of CO2 Uptake by Poly(ethyleneimine) Using Zirconosilicate Supports
Abstract
The CO(2) adsorption characteristics of prototypical poly(ethyleneimine)/silica composite adsorbents can be drastically enhanced by altering the acid/base properties of the oxide support via incorporation of Zr into the silica support. Introduction of an optimal amount of Zr resulted in a significant improvement in the CO(2) capacity and amine efficiency under dilute (simulated flue gas) and ultradilute (simulated ambient air) conditions. Adsorption experiments combined with detailed characterization by thermogravimetric analysis, temperature-programmed desorption, and in situ FT-IR spectroscopy clearly demonstrate a stabilizing effect of amphoteric Zr sites that enhances the adsorbent capacity, regenerability, and stability over continued recycling. It is suggested that the important role of the surface properties of the oxide support in these polymer/oxide composite adsorbents has been largely overlooked and that the properties may be even further enhanced in the future by tuning the acid/base properties of the support.
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Citations
Cites
Carbon capture and storage: how green can black be
Haszeldine, R. S. (2009) · Science · doi:10.1126/science.1172246 · Cited by 2,021
Cited by
Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Self-citationNanotechnology for Environmental Remediation: Materials and Applications
Guerra, F. D., Attia, M. F., Whitehead, D. C., & Alexis, F. (2018) · Molecules · doi:10.3390/molecules23071760 · Cited by 787
Sorbents for the Direct Capture of CO 2 from Ambient Air
Shi, X., Xiao, H., Azarabadi, H., Song, J., Wu, X., Chen, X., & Lackner, K. S. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201906756 · Cited by 679
Porous Inorganic Membranes for CO2 Capture: Present and Prospects
Pera-Titus, M. (2014) · Chemical Reviews · doi:10.1021/cr400237k · Cited by 614
Sui, Z.-Y., Cui, Y., Zhu, J.-H., & Han, B.-H. (2013) · ACS Applied Materials & Interfaces · doi:10.1021/am402661t · Cited by 437
Metadata
- Authors
- Kuwahara, Y., Kang, D.-Y., Copeland, J. R., Brunelli, N. A., Didas, S. A., Bollini, P., Sievers, C., Kamegawa, T., Yamashita, H., & Jones, C. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-06-20
- Volume
- 134
- Issue
- 26
- Pages
- 10757-10760
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2329367218
- Cited by
- 236
- References
- 1
- FWCI
- 39.69
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kuwahara, Y., Kang, D.-Y., Copeland, J. R., Brunelli, N. A., Didas, S. A., Bollini, P., Sievers, C., Kamegawa, T., Yamashita, H., & Jones, C. W. (2012). Dramatic Enhancement of CO2 Uptake by Poly(ethyleneimine) Using Zirconosilicate Supports. Journal of the American Chemical Society. https://doi.org/10.1021/ja303136e
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