The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis
Abstract
The search for efficient catalysts to face modern energy challenges requires evaluation and comparison through reliable methods. Catalytic current efficiencies may be the combination of many factors besides the intrinsic chemical properties of the catalyst. Defining turnover number and turnover frequency (TOF) as reflecting these intrinsic chemical properties, it is shown that catalysts are not characterized by their TOF and their overpotential (η) as separate parameters but rather that the parameters are linked together by a definite relationship. The log TOF-η relationship can often be linearized, giving rise to a Tafel law, which allows the characterization of the catalyst by the value of the TOF at zero overpotential (TOF(0)). Foot-of-the-wave analysis of the cyclic voltammetric catalytic responses allows the determination of the TOF, log TOF-η relationship, and TOF(0), regardless of the side-phenomena that interfere at high current densities, preventing the expected catalytic current plateau from being reached. Strategies for optimized preparative-scale electrolyses may then be devised on these bases. The validity of this methodology is established on theoretical grounds and checked experimentally with examples taken from the catalytic reduction of CO(2) by iron(0) porphyrins.
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Cites
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,310
Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels
Benson, E. E., Kubiak, C. P., Sathrum, A. J., & Smieja, J. M. (2009) · Chem. Soc. Rev. · doi:10.1039/b804323j · Cited by 2,059
Artero, V., Chavarot‐Kerlidou, M., & Fontecave, M. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007987 · Cited by 1,393
Du, P., & Eisenberg, R. (2012) · Energy & Environmental Science · doi:10.1039/c2ee03250c · Cited by 1,350
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects
Savéant, J.-M. (2008) · Chemical Reviews · doi:10.1021/cr068079z · Cited by 978
Self-citationDevelopment of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation
Rakowski Dubois, M., & Dubois, D. L. (2009) · Accounts of Chemical Research · doi:10.1021/ar900110c · Cited by 823
Making Oxygen with Ruthenium Complexes
Concepcion, J. J., Jurss, J. W., Brennaman, M. K., Hoertz, P. G., Patrocinio, A. O. T., Murakami Iha, N. Y., Templeton, J. L., & Meyer, T. J. (2009) · Accounts of Chemical Research · doi:10.1021/ar9001526 · Cited by 821
Savéant, J. (2006) · Wiley eBooks · doi:10.1002/0471758078 · Cited by 743
Self-citationHu, X., Brunschwig, B. S., & Peters, J. C. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067876b · Cited by 697
Small molecule mimics of hydrogenases: hydrides and redox
Gloaguen, F., & Rauchfuss, T. B. (2009) · Chem. Soc. Rev. · doi:10.1039/b801796b · Cited by 645
Bourrez, M., Molton, F., Chardon‐Noblat, S., & Deronzier, A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103616 · Cited by 590
Bhugun, I., Lexa, D., & Savéant, J.-M. (1996) · Journal of the American Chemical Society · doi:10.1021/ja9534462 · Cited by 374
Self-citationElectrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles
McCrory, C. C. L., Uyeda, C., & Peters, J. C. (2012) · Journal of the American Chemical Society · doi:10.1021/ja210661k · Cited by 351
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Metadata
- Authors
- Costentin, C., Drouet, S., Robert, M., & Savéant, J.-M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-06-27
- Volume
- 134
- Issue
- 27
- Pages
- 11235-11242
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2332448579
- Cited by
- 849
- References
- 13
- FWCI
- 11.30
- Type
- journal article
- Language
- en
- Open access
- closed
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