The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts
Abstract
The oxygen reduction reaction (ORR) is a key component of biological processes and energy technologies. This Review provides a comprehensive report of soluble molecular catalysts and electrocatalysts for the ORR. The precise synthetic control and relative ease of mechanistic study for homogeneous molecular catalysts, as compared to heterogeneous materials or surface-adsorbed species, enables a detailed understanding of the individual steps of ORR catalysis. Thus, the Review places particular emphasis on ORR mechanism and thermodynamics. First, the thermochemistry of oxygen reduction and the factors influencing ORR efficiency are described to contextualize the discussion of catalytic studies that follows. Reports of ORR catalysis are presented in terms of their mechanism, with separate sections for catalysis proceeding via initial outer- and inner-sphere electron transfer to O 2 . The rates and selectivities (for production of H 2 O 2 vs H 2 O) of these catalysts are provided, along with suggested methods for accurately comparing catalysts of different metals and ligand scaffolds that were examined under different experimental conditions.
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Cites
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Reactivity of HO2/O− 2 radicals in aqueous solution
Bielski, B. H. J., Cabelli, D. E., Arudi, R. L., & Ross, A. B. (1985) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555739 · Cited by 2,169
Cited by
Lattice-strained metal–organic-framework arrays for bifunctional oxygen electrocatalysis
Cheng, W., Zhao, X., Su, H., Tang, F., Che, W., Zhang, H., & Liu, Q. (2019) · Nature Energy · doi:10.1038/s41560-018-0308-8 · Cited by 1,016
Gao, J., Yang, H. B., Huang, X., Hung, S.-F., Cai, W., Jia, C., Miao, S., Chen, H. M., Yang, X., Huang, Y., et al. (2020) · Chem · doi:10.1016/j.chempr.2019.12.008 · Cited by 734
Singh, S. K., Takeyasu, K., & Nakamura, J. (2019) · Advanced Materials · doi:10.1002/adma.201804297 · Cited by 733
Chen, K., Liu, K., An, P., Li, H., Lin, Y., Hu, J., Jia, C., Fu, J., Li, H., Liu, H., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-18062-y · Cited by 678
Liu, L., Gao, M.-Y., Yang, H., Wang, X., Li, X., & Cooper, A. I. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c09979 · Cited by 394
Metadata
- Authors
- Pegis, M. L., Wise, C. F., Martin, D. J., & Mayer, J. M.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-02-06
- Volume
- 118
- Issue
- 5
- Pages
- 2340-2391
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2786699057
- Cited by
- 675
- References
- 3
- FWCI
- 1.46
- Type
- journal article
- Language
- en
- Open access
- closed
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- Pegis, M. L., Wise, C. F., Martin, D. J., & Mayer, J. M. (2018). Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.7b00542
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