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Chemical Intercalation of Zerovalent Metals into 2D Layered Bi2Se3 Nanoribbons
Abstract
We have developed a chemical method to intercalate a variety of zerovalent metal atoms into two-dimensional (2D) layered Bi(2)Se(3) chalcogenide nanoribbons. We use a chemical reaction, such as a disproportionation redox reaction, to generate dilute zerovalent metal atoms in a refluxing solution, which intercalate into the layered Bi(2)Se(3) structure. The zerovalent nature of the intercalant allows superstoichiometric intercalation of metal atoms such as Ag, Au, Co, Cu, Fe, In, Ni, and Sn. We foresee the impact of this methodology in establishing novel fundamental physical behaviors and in possible energy applications.
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Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475
Observation of topological order in a superconducting doped topological insulator
Wray, L. A., Xu, S.-Y., Xia, Y., Hor, Y. S., Qian, D., Fedorov, A. V., Lin, H., Bansil, A., Cava, R. J., & Hasan, M. Z. (2010) · Nature Physics · doi:10.1038/nphys1762 · Cited by 464
Amphoteric nature of copper impurities in Bi2Se3 crystals
Vaško, A., Tichý, L., Horák, J., & Weissenstein, J. (1974) · Applied Physics · doi:10.1007/bf00928132 · Cited by 77
Cited by
Recent progress on 2D magnets: Fundamental mechanism, structural design and modification
Jiang, X., Liu, Q., Xing, J., Liu, N., Guo, Y., Liu, Z., & Zhao, J. (2021) · Applied Physics Reviews · doi:10.1063/5.0039979 · Cited by 445
Engineering covalently bonded 2D layered materials by self-intercalation
Zhao, X., Song, P., Wang, C., Riis-Jensen, A. C., Fu, W., Deng, Y., Wan, D., Kang, L., Ning, S., Dan, J., et al. (2020) · Nature · doi:10.1038/s41586-020-2241-9 · Cited by 325
Ultrafast fiber lasers mode-locked by two-dimensional materials: review and prospect
Jiang, T., Yin, K., Wang, C., You, J., Ouyang, H., Miao, R., Zhang, C., Wei, K., Li, H., Chen, H., et al. (2020) · Photonics Research · doi:10.1364/prj.8.000078 · Cited by 319
Metadata
- Authors
- Koski, K. J., Wessells, C. D., Reed, B. W., Cha, J. J., Kong, D., & Cui, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-08-08
- Volume
- 134
- Issue
- 33
- Pages
- 13773-13779
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2327640115
- Cited by
- 207
- References
- 3
- FWCI
- 4.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Koski, K. J., Wessells, C. D., Reed, B. W., Cha, J. J., Kong, D., & Cui, Y. (2012). Chemical Intercalation of Zerovalent Metals into 2D Layered Bi2Se3 Nanoribbons. Journal of the American Chemical Society. https://doi.org/10.1021/ja304925t
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