The DOI matches its Crossref record.
Tuning Cooperativity by Controlling the Linker Length of Silica-Supported Amines in Catalysis and CO2 Capture
Abstract
Cooperative interactions between aminoalkylsilanes and silanols on a silica surface can be controlled by varying the length of the alkyl linker attaching the amine to the silica surface from C1 (methyl) to C5 (pentyl). The linker length strongly affects the catalytic cooperativity of amines and silanols in aldol condensations as well as the adsorptive cooperativity for CO(2) capture. The catalytic cooperativity increases with the linker length up to propyl (C3), with longer, more flexible linkers (up to C5) providing no additional benefit or hindrance. Short linkers (C1 and C2) limit the beneficial amine-silanol cooperativity in aldol condensations, resulting in lower catalytic rates than with the C3+ linkers. For the same materials, the adsorptive cooperativity exhibits similar trends for CO(2) capture efficiency.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Self-citationCooperativity in Noncovalent Interactions
Mahadevi, A. S., & Sastry, G. N. (2016) · Chemical Reviews · doi:10.1021/cr500344e · Cited by 933
Understanding the Effect of Water on CO2 Adsorption
Kolle, J. M., Fayaz, M., & Sayari, A. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00762 · Cited by 523
Design and fabrication of mesoporous heterogeneous basic catalysts
Sun, L.-B., Liu, X.-Q., & Zhou, H.-C. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00090d · Cited by 386
Single-Component and Binary CO2 and H2O Adsorption of Amine-Functionalized Cellulose
Gebald, C., Wurzbacher, J. A., Borgschulte, A., Zimmermann, T., & Steinfeld, A. (2014) · Environmental Science & Technology · doi:10.1021/es404430g · Cited by 226
Metadata
- Authors
- Brunelli, N. A., Didas, S. A., Venkatasubbaiah, K., & Jones, C. W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-08-20
- Volume
- 134
- Issue
- 34
- Pages
- 13950-13953
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2329287291
- Cited by
- 191
- References
- 0
- FWCI
- 30.87
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Tuning Cooperativity by Controlling the Linker Length of Silica-Supported Amines in Catalysis and CO2 Capture. https://app.cochat.ai/papers/10.1021/ja305601g
- The paper
- Brunelli, N. A., Didas, S. A., Venkatasubbaiah, K., & Jones, C. W. (2012). Tuning Cooperativity by Controlling the Linker Length of Silica-Supported Amines in Catalysis and CO2 Capture. Journal of the American Chemical Society. https://doi.org/10.1021/ja305601g
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
