The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Photodriven Charge Separation Dynamics in CdSe/ZnS Core/Shell Quantum Dot/Cobaloxime Hybrid for Efficient Hydrogen Production
Abstract
Photodriven charge-transfer dynamics and catalytic properties have been investigated for a hybrid system containing CdSe/ZnS core/shell quantum dots (QDs) and surface-bound molecular cobaloxime catalysts. The electron transfer from light-excited QDs to cobaloxime, revealed by optical transient absorption spectroscopy, takes place with an average time constant of 105 ps, followed a much slower charge recombination process with a time constant of ≫3 ns. More interestingly, we also observed photocatalytic hydrogen generation by this QD/cobaloxime hybrid system, with >10,000 turnovers of H(2) per QD in 10 h, using triethanolamine as a sacrificial electron donor. These results suggest that QD/cobaloxime hybrids succeed in coupling single-photon events with multielectron redox catalytic reactions, and such systems could have potential applications in long-lived artificial photosynthetic devices for fuel generation from sunlight.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Dabbousi, B. O., Rodriguez-Viejo, J., Mikulec, F. V., Heine, J. R., Mattoussi, H., Ober, R., Jensen, K. F., & Bawendi, M. G. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp971091y · Cited by 4,229
Cited by
Engineering heterogeneous semiconductors for solar water splitting
Li, X., Yu, J., Low, J., Fang, Y., Xiao, J., & Chen, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta04461d · Cited by 1,888
Recent Progress in Energy‐Driven Water Splitting
Tee, S. Y., Win, K. Y., Teo, W. S., Koh, L., Liu, S., Teng, C. P., & Han, M. (2017) · Advanced Science · doi:10.1002/advs.201600337 · Cited by 962
Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Hildebrandt, N., Spillmann, C. M., Algar, W. R., Pons, T., Stewart, M. H., Oh, E., Susumu, K., Díaz, S. A., Delehanty, J. B., & Medintz, I. L. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00030 · Cited by 730
Hetero-nanostructured suspended photocatalysts for solar-to-fuel conversion
Yuan, Y.-P., Ruan, L.-W., Barber, J., Joachim Loo, S. C., & Xue, C. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee02914c · Cited by 531
Metadata
- Authors
- Huang, J., Mulfort, K. L., Du, P., & Chen, L. X.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-09-27
- Volume
- 134
- Issue
- 40
- Pages
- 16472-16475
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2325010659
- Cited by
- 272
- References
- 1
- FWCI
- 8.50
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
