The DOI matches its Crossref record.
Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst
Abstract
By the use of an N-heterocyclic carbene copper(I) complex as a catalyst, the boracarboxylation of various alkynes (e.g., diaryl alkynes, aryl/alkyl alkynes, and phenylacetylene) with a diborane compound and carbon dioxide has been achieved for the first time, affording the α,β-unsaturated β-boralactone derivatives regio- and stereoselectively via a borylcupration/carboxylation cascade. Some important reaction intermediates were isolated and structurally characterized to clarify the reaction mechanism.
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Cited by
Catalytic conversion of carbon dioxide to carboxylic acid derivatives
Liu, A., Yu, B., & He, L. (2015) · Greenhouse Gases Science and Technology · doi:10.1002/ghg.1461 · Cited by 57
Metadata
- Authors
- Zhang, L., Cheng, J., Carry, B., & Hou, Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-08-23
- Volume
- 134
- Issue
- 35
- Pages
- 14314-14317
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2333791439
- Cited by
- 292
- References
- 0
- FWCI
- 14.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst. https://app.cochat.ai/papers/10.1021/ja3063474
- The paper
- Zhang, L., Cheng, J., Carry, B., & Hou, Z. (2012). Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst. Journal of the American Chemical Society. https://doi.org/10.1021/ja3063474
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
