Catalytic conversion of carbon dioxide to carboxylic acid derivatives
Abstract
Abstract Chemical utilization of the greenhouse gas, i.e., CO2 as an abundant, easily available, and renewable carbon feedstock for producing chemicals, materials, and fuels is attractive as an integral part of the carbon cycle. Based on the principle of CO2 activation and elaborately designed catalysts, various transformation of CO2 can be realized under mild conditions. In particular, establishing practical methodologies for catalytic carboxylation by CO2 as carboxylative reagent would be a fascinating dream for synthetic chemists. This review covers the updated advances in the catalytic conversion of CO2 into carboxylic acid derivatives from alkenes, alkynes, aromatic halides, aromatic C(sp2)‐H bonds, etc.
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Formation of C-C bonds is through direct carboxylation of CO2 with alkenes, alkynes, or aromatic heterocycles, affording carboxylic acid derivatives.
“The formation of C–C bonds is through a direct carboxylation reaction (i.e., carboxylation of CO2 with alkenes, alkynes, or aromatic heterocycles), affording carboxylic acid derivatives as the target products.301,302”
From Technologies and perspectives for achieving carbon neutrality (2021) · cites this paper as [301]
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Technologies and perspectives for achieving carbon neutrality
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- Authors
- Liu, A., Yu, B., & He, L.
- Affiliations
- Nankai University, Tianjin, People’s Republic of China
- Nankai University (CN)
- Corresponding author
- He, Liang‐Nian
- Venue
- Greenhouse Gases Science and Technology
- Publisher
- Wiley
- Published
- 2014-08-24
- Volume
- 5
- Issue
- 1
- Pages
- 17-33
- ISSN
- 2152-3878 (ISSN-L)
- OpenAlex
- W2158667730
- Cited by
- 57
- References
- 103
- Citations by year
- 2025: 1 · 2024: 2 · 2023: 7 · 2022: 6 · 2021: 3 · 2020: 7 · 2019: 3 · 2018: 10 · 2017: 11 · 2016: 6 · 2015: 1
- FWCI
- 2.46
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Greenhouse Gases Science and Technology (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Keywords
- CO2 utilization, CO2 activation, carboxylation, carboxylic acid derivatives, heterogeneous catalysis, alkenes, alkynes, aromatic halides, C(sp2)-H functionalization
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