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Cited by 335

The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.

CO2 Dynamics in a Metal–Organic Framework with Open Metal Sites

Kong, Xueqian, Scott, Eric, Ding, Wen, Mason, Jarad A., Long, Jeffrey R., Reimer, Jeffrey A.·2012·Journal of the American Chemical Society

Abstract

Metal-organic frameworks (MOFs) with open metal sites are promising candidates for CO(2) capture from dry flue gas. We applied in situ(13)C NMR spectroscopy to investigate CO(2) adsorbed in Mg(2)(dobdc) (H(4)dobdc = 2,5-dihydroxyterephthalic acid; Mg-MOF-74, CPO-27-Mg), a key MOF in which exposed Mg(2+) cation sites give rise to exceptional CO(2) capture properties. Analysis of the resulting spectra reveals details of the binding and CO(2) rotational motion within the material. The dynamics of the motional processes are evaluated via analysis of the NMR line shapes and relaxation times observed between 12 and 400 K. These results form stringent and quantifiable metrics for computer simulations that seek to screen and improve the design of new MOFs for CO(2) capture.

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Metadata

Authors
Kong, X., Scott, E., Ding, W., Mason, J. A., Long, J. R., & Reimer, J. A.
Venue
Journal of the American Chemical Society
Published
2012-08-23
Volume
134
Issue
35
Pages
14341-14344
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2148295263
Cited by
335
References
4
FWCI
14.86
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: CO2 Dynamics in a Metal–Organic Framework with Open Metal Sites. https://app.cochat.ai/papers/10.1021/ja306822p
The paper
Kong, X., Scott, E., Ding, W., Mason, J. A., Long, J. R., & Reimer, J. A. (2012). CO2 Dynamics in a Metal–Organic Framework with Open Metal Sites. Journal of the American Chemical Society. https://doi.org/10.1021/ja306822p

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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